Novel membranes based on cellulose for gas separation and green method for their preparing

Authors

  • Valeryia B. Filistovich Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus
  • Tatsiana A. Savitskaya Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus
  • Irina M. Kimlenka Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus
  • Dzmitry D. Hrynshpan Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus
  • Svetlana E. Makarevich Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus
  • Vladimir V. Teplyakov A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninskii Avenue, Moscow 119991, Russia
  • Daria A. Syrtsova A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninskii Avenue, Moscow 119991, Russia

Keywords:

cellulose, chitosan, orthophosphoric acid, composite membranes, gas separation, oxygen, nitrogen, methane, carbon dioxide, fabric support, two-layer film
Supporting Agencies
The work was financially supported by Belarusian Republican Foundation for Fundamental Research (grant No. X18P-176) and Russian Foundation for Basic Research (grant No. 18-53-00017).

Abstract

A «green» method of obtaining gas separation composite membranes from cellulose solutions and its mixtures with chitosan in orthophosphoric acid is proposed for industrial use, and differs from the viscose method of producing cellophane and other known methods for producing cellulose gas separation membranes without gaseous emissions and wastewater. It is shown that new composite cellulose membranes on a viscose fabric substrate are characterized by high productivity and selectivity for O2/ N2 pairs, comparable to the values obtained for known membranes made of synthetic polymers, as well as increased mechanical strength. The developed composite membranes demonstrate an inverse selectivity for the CH4/CO2 pair, which is not typical for gas separation membranes described in the literature with cellulose-based selective layers.

Author Biographies

  • Valeryia B. Filistovich, Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus

    student at the faculty of chemistry

  • Tatsiana A. Savitskaya, Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus

    PhD (chemistry); professor at the department of physical chemistry, faculty of chemistry

  • Irina M. Kimlenka, Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus

    PhD (chemistry); associate professor at the department of radiation chemistry and chemical-pharmaceutical technologies, faculty of chemistry

  • Dzmitry D. Hrynshpan, Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus

    doctor of science (chemistry), full professor; head of the laboratory for cellulose solutions and products of their treatment

  • Svetlana E. Makarevich, Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus

    senior researcher at the laboratory of cellulose solutions and products

  • Vladimir V. Teplyakov, A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninskii Avenue, Moscow 119991, Russia

    doctor of science (chemistry), full professor; head of the laboratory of physico-chemistry of membrane processes

  • Daria A. Syrtsova, A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninskii Avenue, Moscow 119991, Russia

    PhD (chemistry); senior researcher at the laboratory of physico-chemistry of membrane processes

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Published

2019-02-19

Issue

No. 1 (2019): Journal of the Belarusian State University. Chemistry

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Original Articles

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How to Cite

[1]
Filistovich, V.B. et al. 2019. Novel membranes based on cellulose for gas separation and green method for their preparing. Journal of the Belarusian State University. Chemistry. 1 (Feb. 2019), 66–77. DOI:https://doi.org/10.33581/2520-257X-2019-1-66-77.