Adsorption of cefotaxim sodium on activated carbons of various origin

Authors

  • Nastassia V. Lishai Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus https://orcid.org/0000-0002-5977-4022 (unauthenticated)
  • Tatyana A. Savitskaya Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus
  • Nadzeia G. Tsyhankova Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus
  • Dzmitry D. Hrynshpan Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus
  • Oleg A. Ivashkevich Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus

Keywords:

adsorption, multilayer model with saturation, activated carbon, сefotaxime sodium

Abstract

The adsorption of the cephalosporin antibiotic sodium cefotaxime (CEFOT) on two activated carbons in the temperature range 288–313 K was under study. Experimental charcoal AC obtained from hydrolysis lignin was established to be mesoporous. It demonstrates greater CEFOT adsorption activity than the commercially available charcoal OU-A made from wood and characterized by both micro- and mesoporous structure. The surface modification of both activated carbons by a water-soluble polyelectrolyte cellulose acetate sulfate in the form of sodium salt (Na-CAS) leads to an increase in specific adsorption. The multilayer model with saturation (MMS) was used for data analysis. As a result, the number of molecules on the adsorption center, the density of adsorption centers, the total number of formed layers and the energy characteristics of adsorbate – adsorbent interactions at the interface and adsorbate – adsorbate ones within the adsorption layer were estimated.

Author Biographies

  • Nastassia V. Lishai, Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus

    postgraduate student at the department of inorganic chemistry, faculty of chemistry

  • Tatyana A. Savitskaya, Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus

    PhD (chemistry); professor at the department of physical chemistry and deputy dean for research, faculty of chemistry

  • Nadzeia G. Tsyhankova, Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus

    leading researcher at the laboratory of cellulose solutions and products of their treatment

  • Dzmitry D. Hrynshpan, Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus

    doctor of science (chemistry), full professor; head of the laboratory of cellulose solutions and products of their treatment

  • Oleg A. Ivashkevich, Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus

    academician of the National Academy of Sciences of Belarus, doctor of science (chemistry), full professor; first vice-rector

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Published

2020-03-06

Issue

No. 1 (2020): Journal of the Belarusian State University. Chemistry

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Original Articles

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How to Cite

[1]
Lishai, N.V. et al. 2020. Adsorption of cefotaxim sodium on activated carbons of various origin. Journal of the Belarusian State University. Chemistry. 1 (Mar. 2020), 95–107. DOI:https://doi.org/10.33581/2520-257X-2020-1-95-107.