Synthesis and some properties of new functionally substituted poly-5-vinyltetrazoles

Authors

  • Yuri V. Grigoriev Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieningradskaja Street, Minsk 220006, Belarus https://orcid.org/0000-0002-8153-835X
  • Dmitriy I. Shiman Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieningradskaja Street, Minsk 220006, Belarus
  • Inna M. Grigorieva Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieningradskaja Street, Minsk 220006, Belarus
  • Ekaterina A. Abramovich Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieningradskaja Street, Minsk 220006, Belarus
  • Darya S. Kosterova Belarusian State University, 4 Niezaliezhnasci Avenue, Minsk 220030, Belarus
  • Oleg A. Ivashkevich Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieningradskaja Street, Minsk 220006, Belarus

Keywords:

poly-5-vinyltetrazole, functionalisation, solubility, glass transition temperature, thermolysis
Supporting Agencies
The research was supported by the Ministry of Education of the Republic of Belarus (assignment 2.1.01.01 of the state programme of scientific research «Chemical processes, reagents and technologies, bioregulators and bioorgchemistry», state registration No. 20210515).

Abstract

It was found that the solubility of poly-5-vinyltetrazole in organic solvents can be extended by its reprecipitation from dimethylformamide solutions into trifluoroacetic acid, as well as into a mixture of carboxylic acids with diethyl ether, acetone or tetrahydrofuran. Methods for the preparation of N-alkyl-poly-5-vinyltetrazoles have been proposed. It has been found that the introduction of an n-alkyl substituent into the tetrazole fragment of poly-5-vinyltetrazole leads to increasing of solubility of resulted polymers in a wide range of organic solvents, while glass transition temperature of polymers decreases with increasing length of the hydrocarbon substituent. A method for the synthesis of new poly-5-vinyltetrazole derivatives containing both N-methylated and N, N′-dimethyl (quaternised) has been developed, which give possibility to obtain polymers with adjustable ratio of methylated and quaternised tetrazole cycles. It was shown that the value of specific heat of thermal decomposition of N, N′-dimethyl-poly-5-vinyltetrazolium perchlorates increases with growing degree of quaternisation. The results of these studies can be used for the synthesis of N-substituted poly-5-vinyltetrazoles with desired structure and physico-chemical properties.

Author Biographies

  • Yuri V. Grigoriev, Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieningradskaja Street, Minsk 220006, Belarus

    PhD (chemistry), docent; head of the laboratory for chemistry of condensed systems

  • Dmitriy I. Shiman, Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieningradskaja Street, Minsk 220006, Belarus

    PhD (chemistry), docent; leading researcher at the laboratory of catalysis of polymerisation processes

  • Inna M. Grigorieva, Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieningradskaja Street, Minsk 220006, Belarus

    researcher at the laboratory for chemistry of condensed systems

  • Ekaterina A. Abramovich, Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieningradskaja Street, Minsk 220006, Belarus

    junior researcher at the centre for collective use of unique scientific equipment

  • Darya S. Kosterova, Belarusian State University, 4 Niezaliezhnasci Avenue, Minsk 220030, Belarus

    postgraduate student at the department of macromolecular compounds, faculty of chemistry

  • Oleg A. Ivashkevich, Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieningradskaja Street, Minsk 220006, Belarus

    doctor of sciences (chemistry), academician of the National Academy of Sciences of Belarus; chief researcher at the laboratory for chemistry of condensed systems

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Published

2025-04-24

Issue

No. 1 (2025): Journal of the Belarusian State University. Chemistry

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Original Articles

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How to Cite

Synthesis and some properties of new functionally substituted poly-5-vinyltetrazoles. (2025). Journal of the Belarusian State University. Chemistry, 1, 13-21. https://journals.bsu.by/index.php/chemistry/article/view/6684