Influence of aluminium coagulants composition on colloidal characteristics of humic substances dispersions

Authors

  • Alesia V. Zyhmant Research Institute for Physical Chemical Problems of the Belarusian State University, Leningradskaya street, 14, 220006, Minsk
  • Tatsiana A. Savitskaya Research Institute for Physical Chemical problems of the Belarusian State University, Leningradskaya street, 14, 220006, Minsk
  • Nadzeia G. Tsyhankova Research Institute for Physical Chemical problems of the Belarusian State University, Leningradskaya street, 14, 220006, Minsk
  • Dzmitry D. Hrynshpan Research Institute for Physical Chemical problems of the Belarusian State University, Leningradskaya street, 14, 220006, Minsk

Keywords:

dispersions, coagulants, aluminium sulphate, pentahydroxodialuminium chloride, sedimentation rate, kaolin, humic substances

Abstract

The effect of aluminium coagulants composition on colloidal characteristics of humic substances dispersions (diameter, particle size distribution, density and sedimentation rate of aggregates) was investigated by using of laser diffraction method. Aggregates shape and structure were characterized by the experimentally determined fractal dimension values in the comparison with computer simulation data. The mixed aggregates size in the humic substances dispersions was founded to increase in the case of aluminium sulphate as a coagulant according to the aluminium hydroxide dispersion when alone. Otherwise, the density of mixed aggregates is lower than for the aggregates in aluminium hydroxide dispersion. In the case of pentahydroxodialuminium chloride, the reverse relationships were observed.

Author Biographies

  • Alesia V. Zyhmant, Research Institute for Physical Chemical Problems of the Belarusian State University, Leningradskaya street, 14, 220006, Minsk

    junior researcher

  • Tatsiana A. Savitskaya, Research Institute for Physical Chemical problems of the Belarusian State University, Leningradskaya street, 14, 220006, Minsk

    PhD (chemistry), docent; professor at the department of physical chemistry, leading researcher

  • Nadzeia G. Tsyhankova, Research Institute for Physical Chemical problems of the Belarusian State University, Leningradskaya street, 14, 220006, Minsk

    PhD (chemistry); leading researcher

  • Dzmitry D. Hrynshpan, Research Institute for Physical Chemical problems of the Belarusian State University, Leningradskaya street, 14, 220006, Minsk

    doctor of science (chemistry), full professor; head of the laboratory of cellulose solutions and products of their treatment

References

  1. Rodríguez J., Schlenger P., García-Valverde M. Monitoring changes in the structure and properties of humic substances following ozonation using UV-Vis, FTIR and 1H NMR techniques. Sci. Total Environment. 2016. Vol. 541. P. 623–637.
  2. Lishtvan I. I., Kaputskiy F. N., Yanuta Yu. G., et al. Humic acids and metallic ion interaction and metal-humic complexes structure. Vestnik BSU. Ser. 2, Khim. Biol. Geogr. 2012. No. 2. P. 12–16 (in Russ.).
  3. Exall K. N., Vanloon G. W. Using Coagulants to Remove Organic Matter. J. AWWA. 2000. Vol. 92, No. 11. P. 93–102.
  4. Orlov D. S. Svoistva i funktsii guminovykh veshchestv. Mosc., 1993 (in Russ.).
  5. Avvakumova N. P. Humic substances as a factor of biosystems protection from ecotoxicants. Izv. Samar. nauchn. tsentra Ross. akad. nauk. 2009. Vol. 11, No. 1 (2). P. 197–201 (in Russ.).
  6. Ivkyn P. A. Development of highly colored and low turbid water treatment technology. Vodosnabzhenie i san. techn. 2010. No. 7. P. 38–47 (in Russ.).
  7. Hu Ch., Liu H., Qu J., et al. Coagulation behavior of aluminum salts in eutrophic water: significance of Al13 species and pH control. Environ. Sci. Technol. 2006. Vol. 40. P. 325–331.
  8. Van Benschoten J. E., Edzwald J. Chemical aspects of coagulation using aluminum salts – 2. Coagulation of fulvic acid using alum and polyaluminum chloride. Water Res. 1990. Vol. 24. P. 1527–1536.
  9. Shi B., Wei Q., Wang D., et al. Coagulation of humic acid: The performance of preformed and non-preformed Al species. Colloids Surf. A. 2007. Vol. 296. P. 141–148.
  10. Duan J., Wang J., Guo T., et al. Zeta potentials and sizes of aluminum salt precipitates – Effect of anions and organics and implications for coagulation mechanisms. J. Water Proc. Eng. 2014. Vol. 4. P. 224–232.
  11. Tang H., Xiao F., Wang D. Speciation, stability, and coagulation mechanisms of hydroxyl aluminum clusters formed by PACl and alum: A critical review. Adv. Colloid Interface Sci. 2015. Vol. 226, part A. Р. 78–85.
  12. Wu Ch.,Wang L., Hu B., et al. Influential factors of formation kinetics of flocs produced by water treatment coagulants. J. Environ. Sci. 2013. Vol. 25, No. 5. P. 1015–1022.
  13. Feng R.,Yue Q., Gao B., et al. Coagulation performance and membrane fouling of different aluminum species during coagulation/ ultrafiltration combined process. Chem. Eng. J. 2015. Vol. 262. P. 1161–1167.
  14. Yua W., Gregory J., Camposa L. C. Breakage and re-growth of flocs: Effect of additional doses of coagulant species. Water Res. 2011. Vol. 45. P. 6718–6724.
  15. Spravochnik khimika : in 6 vol. Mosc. ; Leningr., 1963. Vol. 2 (in Russ.).
  16. Dinar E., Mentel T. F., Rudich Y. The density of humic acids and humic like substances (HULIS) from fresh and aged wood burning and pollution aerosol particles. Atmos. Chem. Phys. 2006. Vol. 6. P. 5213–5224.
  17. Babenkov E. D. Ochistka vody koagulyantami. Mosc., 1977 (in Russ.).
  18. Frolov Yu. G. Kurs kolloidnoi khimii. Poverkhnostnye yavleniya i dispersnye sistemy. Mosc., 1988 (in Russ.).
  19. Pabst W., Gregorová E. Characterization of particles and particle systems. Prague, 2007.
  20. Yan W., Yu G. B., Ming X. X., et al. The effect of total hardness on the coagulation performance of aluminum salts with different Al species. Sep. Purif. Technol. 2009. Vol. 66. P. 457–462.
  21. Heinson W. R., Sorensen C. M., Chakrabarti A. A three parameter description of the structure of diffusion limited cluster fractal aggregates. J. Colloid Interface Sci. 2012. Vol. 375. P. 65–69.
  22. Zyhmant A. V., Savitskaya T. A., Tsyhankova N. G., et al. Influence of aluminium coagulants composition on colloidal characteristics of kaolin dispersions. Vesci Nac. akad. navuk Belarusi. Ser. himichnyh navuc. 2017. No. 1. P. 49–56 (in Russ.).

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Published

2017-11-29

How to Cite

[1]
Zyhmant, A.V. et al. 2017. Influence of aluminium coagulants composition on colloidal characteristics of humic substances dispersions. Journal of the Belarusian State University. Chemistry. 1 (Nov. 2017), 65–73.