Microtribological behavior of metal-matrix nanocomposites based on the nanocontainer-like layered oxides

Authors

  • Alexander S. Logvinovich Belarusian State University, Niezaliežnasci Avenue, 4, 220030, Minsk, Belarus
  • Tatsiana V. Sviridova Belarusian State University, Niezaliežnasci Avenue, 4, 220030, Minsk, Belarus
  • Dmitri V. Sviridov Belarusian State University, Niezaliežnasci Avenue, 4, 220030, Minsk, Belarus
  • Alexei V. Kaparikha Belarusian State University, Niezaliežnasci Avenue, 4, 220030, Minsk, Belarus

Keywords:

metal-matrix composites, molybdenum trioxide, benzotriazole, microtribology, atomic-force microscopy, container systems
Supporting Agencies
The work was carried partially out within the framework of the Belarusian Republican for Foundation for Fundamental Research project (grant No. X17PM-073).

Abstract

The electrochemical codeposition of nickel with the dispersed molybdenum oxide of layered structure yields metalmatrix composites in which the second phase is capable to play a role of container retaining organics in its internal volume. It is shown that the intercalation of benzotriazole (a well-known corrosion inhibitor) into the interlayer volume of MoO3 ensures an effective suppression of tribocorrosion of matrix metal.

Author Biographies

  • Alexander S. Logvinovich, Belarusian State University, Niezaliežnasci Avenue, 4, 220030, Minsk, Belarus

    postgraduate student at the department of inorganic chemistry, faculty of chemistry

  • Tatsiana V. Sviridova, Belarusian State University, Niezaliežnasci Avenue, 4, 220030, Minsk, Belarus

    PhD (chemistry); associate professor at the department of inorganic chemistry, faculty of chemistry

  • Dmitri V. Sviridov, Belarusian State University, Niezaliežnasci Avenue, 4, 220030, Minsk, Belarus

    corresponding member of the National Academy of Sciences of Belarus, doctor of science (chemistry); dean of the faculty of chemistry

  • Alexei V. Kaparikha, Belarusian State University, Niezaliežnasci Avenue, 4, 220030, Minsk, Belarus

    PhD (chemistry); leading researcher at the department of inorganic chemistry, faculty of chemistry

References

  1. Sviridova T. V., Stepanova L. I., Sviridov D. V. Electrochemical synthesis of Ni-MoO3 composite films: redox-mediated mechanism of electrochemical growth of metal-matrix composite. J. Solid State Electrochem. 2012. Vol. 16, issue 12. P. 3799–3803. DOI: 10.1007/s10008-012-1816-2.
  2. Sviridova T. V. [Composition materials: metal-matrix composites]. Minsk : BSU, 2012 (in Russ.).
  3. Sviridova T. V., Stepanova L. I., Sviridov D. V. Nano- and microcrystals of molybdenum trioxide and metal-matrix composites on their basis. Molybdenum: Characteristics, Production Applications. New York, 2012. P. 147–179.
  4. Sviridova T. V., Logvinovich A. S., Sviridov D. V. Electrochemical codeposition of nickel and molybdenum trioxide with controlled redox-activity. Dokl. Natl. Acad. Sci. Belarus. 2015. Vol. 59, No. 2. P. 68–71 (in Russ.).
  5. Sviridova T. V., Logvinovich A. S., Sviridov D. V. Electrochemical growing of Ni-MoO3 nanocomposite coatings via redox mechanism. Surf. Coat. Technol. 2017. Vol. 319. P. 6–11. DOI: 10.1016/j.surfcoat.2017.03.41.
  6. Igual Muñoz A., Garcia Antón J., Guiñón J. L., et al. Comparison of inorganic inhibitors of copper, nickel and copper-nickels in aqueous lithium bromide solution. Electrochim. Acta. 2004. Vol. 50. P. 957–966. DOI: 10.1016/j.electacta.2004.07.048.

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Published

2018-04-30

Issue

No. 1 (2018): Journal of the Belarusian State University. Chemistry

Section

Original Articles

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How to Cite

[1]
Logvinovich, A.S. et al. 2018. Microtribological behavior of metal-matrix nanocomposites based on the nanocontainer-like layered oxides. Journal of the Belarusian State University. Chemistry. 1 (Apr. 2018), 54–60.