Preparation and study of thermostable composites based on solid magnesium phosphate and calcium phosphate binders
Keywords:
thermostable composites, solid phosphate binders, magnesium phosphate binder, calcium phosphate binder, hybrid calcium magnesium phosphate binders, aluminum oxide, aluminum nitride, dolomiteAbstract
Thermostable composite materials based on solid magnesium phosphate and calcium phosphate, as well as hybrid calcium magnesium phosphate binders have been developed and investigated. Thermal and phase transformations of the phosphate composites have been studied. Strength characteristics of composite materials have been determined in the temperature range of 20–1000 °C. It is shown that the obtained phosphate composites have high strength properties (compressive strength reaches 120–130 MPa) and are characterised by high thermal stability in the temperature range up to 1000 °С. The low weight loss of the studied composites (no more than 10 %) and the absence of significant thermal effects indicate that they are promising for use as a thermostable matrix for obtaining functional composite materials.
References
- Trombetta R, Inzana JA, Schwarz EM, Kates SL, Awad HA. 3D printing of calcium phosphate ceramics for bone tissue engineering and drug delivery. Annals of Biomedical Engineering. 2017;45(1):23–44. DOI: 10.1007/s10439-016-1678-3.
- Othman Z, Mohren RJC, Cillero-Pastor B, Shen Z, Lacroix YSNW, Guttenplan APM, et al. Comparative proteomic analysis of human mesenchymal stromal cell behavior on calcium phosphate ceramics with different osteoinductive potential. Materials Today Bio. 2020;7:100066. DOI: 10.1016/j.mtbio.2020.100066.
- Yan Tao, Lai Zhenyu, Ren Chunrong, Wang Yuanyuan, Hu Zhichao, He Xin, et al. Study on solidification properties of chemically bonded phosphate ceramics for cesium radionuclides. Ceramics International. 2020;46(10 part A):14964–14971. DOI: 10.1016/j.ceramint.2020.03.025.
- Plyushch A, Macutkevic J, Svirskas S, Banys J, Plausinaitiene V, Bychanok Dz, et al. Silicon carbide/phosphate ceramics composite for electromagnetic shielding applications: whiskers vs particles. Applied Physics Letters. 2019;114(18):183105. DOI: 10.1063/1.5093421.
- Tingjie Chen, Zhenzeng Wu, Xiaodong Alice Wang, Wei Wang, Daobang Huang, Qihua Wei, et al. Hierarchical lamellar aluminophosphate materials with porosity as ecofriendly inorganic adhesive for wood-based boards. ACS Sustainable Chemistry & Engineering. 2018;6(5):6273–6280. DOI: 10.1021/acssuschemeng.8b00078.
- Miguel VC, Fini DS, Pinto VS, Moreira MH, Pandolfelli VC, Luz AP. Crack-free caustic magnesia-bonded refractory castables. Ceramics International. 2021;47(12):17255–17261. DOI: 10.1016/j.ceramint.2021.03.036.
- Abyzov VA. Lightweight refractory concrete based on aluminum-magnesium-phosphate binder. Procedia Engineering. 2016;150:1440–1445. DOI: 10.1016/j.proeng.2016.07.077.
- Luz AP, Lopes SJS, Gomes DT, Pandolfelli VC. High-alumina chemically bonded refractory castables containing liquid or powdered binders. Refractories WORLDFORUM. 2018;10(2):68–73.
- Brokesh AM, Gaharwar AK. Inorganic biomaterials for regenerative medicine. ACS Applied Materials & Interfaces. 2020;12(5):5319–5344. DOI: 10.1021/acsami.9b17801.
- Kingery WD. Fundamental study of phosphate bonding in refractories. I. Literature review. Journal of the American Ceramic Society. 1950;33(8):239–241. DOI: 10.1111/j.1151-2916.1950.tb14171.x.
- Kingery WD. Fundamental study of phosphate bonding in refractories. IV. Mortars bonded with monoaluminum and monomagnesium phosphate. Journal of the American Ceramic Society. 1952;35(3):61–63. DOI: 10.1111/j.1151-2916.1952.tb13069.x.
- Duderov GN, Ryzhikov VI. [On the use of aluminum phosphates as a binder for highly refractory coatings for metal]. Trudy Moskovskogo khimiko-tekhnologicheskogo instituta imeni D. I. Mendeleeva. 1957;24:190–198. Russian.
- Sudakas LG. Fosfatnye vyazhushchie sistemy [Phosphate binding systems]. Saint Petersburg: Kvintet; 2008. 260 p. Russian.
- Sychev MM. Neorganicheskie klei [Inorganic adhesives]. 2nd edition. Leningrad: Khimiya; 1986. 152 p. Russian.
- Kopeikin VA, Petrova AP, Rashkovan IL. Materialy na osnove metallofosfatov [Materials based on metal phosphates]. Moscow: Khimiya; 1976. 200 p. Russian.
- Kopeikin VA, Kliment’eva VS, Krasnyi BL. Ogneupornye rastvory na fosfatnykh svyazuyushchikh [Refractory solutions based on phosphate binders]. Moscow: Metallurgiya; 1986. 240 p. Russian.
- Petrova AP. Termostoikie klei [Thermoresistant adhesives]. Moscow: Khimiya; 1977. 200 p. Russian.
- Lapko KN, Vydumchik GN, Galeeva NI. The usage of phosphatic bonding agents for dry building mixture production. ALITinform: Cement. Concrete. Dry Mixtures. 2010;6:78–83. Russian.
- Lapko KN, Apanasevich NS, Shulga TN, Kudlash AN, Galeyeva NN. Dry building mixtures based on solid phosphate binders for thermostable functional composite materials. ALITinform: Cement. Concrete. Dry Mixtures. 2015;2–3:78–83. Russian.
- Apanasevich NS, Kudlash AN, Lapko KN. [Thermostable composites based on solid magnesium and calcium phosphate binders]. In: Babkin OE, Il’֦ina VV, Panteleev IB, Strokova VV, editors. Innovatsionnye materialy i tekhnologii v dizaine. VI Vserossiiskaya nauchno-prakticheskaya konferentsiya s uchastiem molodykh uchenykh; 26–27 marta 2020 g.; Sankt-Peterburg, Rossiya [Innovative materials and technologies in design. 6th All-Russian scientific and practical conference with the participation of young scientists; 2020 March 26–27; Saint Petersburg, Russia]. Saint Petersburg: SPbGIKiT; 2020. p. 56–57. Russian.
- Wagh AS. Chemically bonded phosphate ceramics. [S. l.]: Elsevier; 2004. 304 p. DOI: 10.1016/B978-0-08-044505-2.X5000-5.
- Kanazawa T. Inorganic phosphate materials. Oxford: Elsevier Science & Technology; 1989. 306 p. Russian edition: Kanazava T. Neorganicheskie fosfatnye materialy. Shpak AP, Karbovskii VL, translators. Kyiv: Naukova dumka; 1998. 297 p.
- Budnikov PP, Khoroshavin LB. Ogneupornye betony na fosfatnykh svyazkakh [Refractory concretes with phosphate binders]. Moscow: Metallurgiya; 1971. 192 p. Russian.
- Apanasevich N, Sokol А, Lapko K, Kudlash A, Lomonosov V, Plyushch A, et al. Phosphate ceramics – carbon nanotubes composites: liquid aluminum phosphate vs solid magnesium phosphate binder. Ceramics International. 2015;41(9 part B):12147–12152. DOI: 10.1016/j.ceramint.2015.06.033.
- Apanasevich NS, Lapko KN, Kudlash AN, Sokol AA, Lomonosov VA, Lesnikovich AI, et al. [Thermostable composite nanomaterials based on solid magnesium phosphate binder]. Nano Studies. 2015;12:197–204. Russian.
- Shchegrov LN. Fosfaty dvukhvalentnykh metallov [Divalent metal phosphates]. Kyiv: Naukova dumka; 1987. 216 p. Russian.
- Khoroshavin LB, Perepelitsyn VA, Kononov VA. Magnezial’nye ogneupory [Magnesia refractories]. Moscow: Intermet inzhiniring; 2001. 576 p. Russian.
- Golynko-Vol’fson SL, Sychev MM, Sudakas LG. Khimicheskie osnovy tekhnologii i primeneniya fosfatnykh svyazok i pokrytii [Chemical bases of technology and application of phosphate binders and coatings]. Leningrad: Khimiya; 1968. 189 p. Russian.
- Konstant ZA, Dindune AP. Fosfaty dvukhvalentnykh metallov [Phosphates of divalent metals]. Riga: Zinatne; 1987. 387 p. Russian.
Downloads
Additional Files
Published
Issue
Section
License
The authors who are published in this journal agree to the following:
- The authors retain copyright on the work and provide the journal with the right of first publication of the work on condition of license Creative Commons Attribution-NonCommercial. 4.0 International (CC BY-NC 4.0).
- The authors retain the right to enter into certain contractual agreements relating to the non-exclusive distribution of the published version of the work (e.g. post it on the institutional repository, publication in the book), with the reference to its original publication in this journal.
- The authors have the right to post their work on the Internet (e.g. on the institutional store or personal website) prior to and during the review process, conducted by the journal, as this may lead to a productive discussion and a large number of references to this work. (See The Effect of Open Access.)














