Molybdenum – vanadium oxide solid solutions used as a tunable redox catalyst for electrochemical growing of nickel-matrix composites

Authors

  • Tatsiana V. Sviridova Belarusian State University, 4 Niezaliezhnasci Avenue, Minsk 220030, Belarus
  • Alexander S. Logvinovich Belarusian State University, 4 Niezaliezhnasci Avenue, Minsk 220030, Belarus
  • Dmitry V. Sviridov Belarusian State University, 4 Niezaliezhnasci Avenue, Minsk 220030, Belarus

Keywords:

metal-matrix composite, molybdenum – vanadium mixed oxide, nucleation, fractal dimension, corrosion stability, wear resistance
Supporting Agencies
This work was carried out with the financial support of the Ministry of Education of the Republic of Belarus within the framework of the state programme of scientific research «Chemical processes and technologies» for 2026–2030 (assignment 2.1.05.2 «Chemically-controlled encapsulating coatings based on inorganic polymers», state registration No. 20261628).

Abstract

 The structure and morphology of electrochemically-derived metal-matrix composite obtained by embedment of redox-active MoO3 : V2O5 oxide particles in the galvanic nickel was investigated. The electron microscopic studies of electrochemically grown composite films and fractal analysis of atomic-force microscopic images provide an evidence that the efficiency of nucleation of matrix metal on the MoO3 : V2O5 particles is dependent on its redox activity yielding fine closely packed crystallites. The resultant composite film Ni – 0.6MoO3 : 0.4V2O5 film demonstrates radically improved (as compared to bare galvanic nickel) wear-resistant and corrosion resistant properties.

Author Biographies

  • Tatsiana V. Sviridova, Belarusian State University, 4 Niezaliezhnasci Avenue, Minsk 220030, Belarus

    doctor of science (chemistry), full professor; professor at the department of inorganic chemistry, faculty of chemistry

  • Alexander S. Logvinovich, Belarusian State University, 4 Niezaliezhnasci Avenue, Minsk 220030, Belarus

    PhD (chemistry), docent; associate professor at the department of inorganic chemistry, faculty of chemistry

  • Dmitry V. Sviridov, Belarusian State University, 4 Niezaliezhnasci Avenue, Minsk 220030, Belarus

    doctor of science (chemistry), corresponding member of  the National Academy of  Sciences of  Belarus, full professor; head of the department of inorganic chemistry, faculty of chemistry

References

  1. Musiani M. Electrodeposition of composites: an expanding subject in electrochemical materials science. Electrochimica Acta. 2000;45(20):3397–3402. DOI: 10.1016/S0013-4686(00)00438-2.
  2. Webb PR, Robertson NL. Electrolytic codeposition of Ni – γ-Al2O3 thin films. journal of the Electrochemical Society. 1994;141(3):669–673. DOI: 10.1149/1.2054789.
  3. Hovestad A, Janssen LJJ. Electrochemical codeposition of inert particles in a metallic matrix. Journal of Applied Electrochemistry. 1995;25(6):519–527. DOI: 10.1007/BF00573209.
  4. Medeliene V, Leinartas K. Corrosion of Ni electrodes modified by SiC, Al2O3 and B4C microparticles in chloride solutions. Chemija. 1999;10(1):22–27.
  5. Sofer Y, Yarnitzky Y, Dirnfeld SF. Evaluation and uses of composite Ni – Co matrix coatings with diamonds on steel applied by electrodeposition. Surface and Coatings Technology. 1990;42(3):227–236. DOI: 10.1016/0257-8972(90)90155-6.
  6. Sviridova TV. Kompozitsionnye materialy: metall-matrichnye kompozity [Composite materials: metal-matrix composites]. Minsk: Belarusian State University; 2012. 272 p. Russian.
  7. Greco VP. Electrocomposites and their benefits. Plating and Surface Finishing. 1989;7:62–67.
  8. Shawki S, Hamid ZA. Deposition of high wear resistance of Ni-composite coatings. Anti-Corrosion Methods and Materials. 1997;44(3):178–185. DOI: 10.1108/00035599710167142.
  9. Vereecken PM, Shao I, Searson PC. Particle codeposition in nanocomposite films. Journal of the Electrochemical Society. 2000;147(7):2572–2575. DOI: 10.1149/1.1393570.
  10. Sviridova TV, Stepanova LI, Sviridov DV. Electrochemical synthesis of Ni – MoO3 composite films: redox-mediated mechanism of electrochemical growth of metal-matrix composite. Journal of Solid State Electrochemistry. 2012;16(12):3799–3803. DOI: 10.1007/s10008-012-1816-2.
  11. Sviridova TV, Logvinovich AS, Sviridov DV. Electrochemical growing of Ni – MoO3 nanocomposite coatings via redox mechanism. Surface and Coatings Technology. 2017;319:6–11. DOI: 10.1016/j.surfcoat.2017.03.041.
  12. Sviridova TV, Antonova AA, Kokorin AI, Degtyarev EN, Sviridov DV. Nanostructured vanadium – molybdenum mixed oxides prepared by the solvothermal method. Russian Journal of Physical Chemistry B. 2015;9(1):22–28. DOI: 10.1134/S199079311501011X.
  13. Sviridova TV, Stepanova LI, Sviridov DV. Nano- and microcrystals of molybdenum trioxide and metal-matrix composites on their basis. In: Ortiz M, Herrera T, editors. Molybdenum: characteristics, production and applications. New York: Nova Science Publishers; 2012. p. 147–179.
  14. Lowenheim FA, editor. Modern electroplating. 3rd edition. New York: John Wiley & Sons; 1974. 832 p.
  15. Douketis С, Wang Z, Haslett TL, Moskovits M. Fractal character of cold-deposited silver films determined by low-temperature scanning tunneling microscopy. Physical Review B. 1995;51(16):11022–11031. DOI: 10.1103/PhysRevB.51.11022.
  16. Zahn W, Zösch A. The dependence of fractal dimension on measuring conditions of scanning probe microscopy. Fresenius’ Journal of Analytic Chemistry. 1999;365(1–3):168–172. DOI: 10.1007/s002160051466.
  17. Sviridova TV, Kokorin AI, Sadovskaya LYu, Sviridov DV. Identification of substitutional solid solutions derived from molybdenum – vanadium oxides using infrared spectroscopy. Journal of Applied Spectroscopy. 2023;90(2):279–283. DOI: 10.1007/s10812-023-01533-7.
  18. López-Medina R, Fierro JLG, Guerrero-Pérez MO, Bañares MA. Nanoscaled rutile active phase in Mo – V – Nb – O supported catalysts for the oxidation of propane to acrylic acid. Applied Catalysis A: General. 2010;375(1):55–62. DOI: 10.1016/j.apcata.2009.12.017.
  19. Nordlinder S, Lindgren J, Gustafsson T, Edström K. The structure and electrochemical performance of Na+, K+, and Ca2+-vanadium oxide nanotubes. Journal of the Electrochemical Society. 2003;150(5):E280. DOI: 10.1149/1.1566414.
  20. Satsuma A, Hattori A, Mizutani K, Furuta A, Miyamoto A, Hattori T, et al. Surface active sites of V2O5 – MoO3 catalysts. The Journal of Physical Chemistry. 1989;93(4):1484–1490. DOI: 10.1021/j100341a059.
  21. Kolbanev IV, Degtyarev EN, Streletskii AN, Kokorin AI. Paramagnetic centers created under mechanochemical treatment of mixed molybdenum – vanadium oxides. Applied Magnetic Resonance. 2016;47(6):575–588. DOI: 10.1007/s00723-016-0778-4.
  22. Sviridova TV, Kokorin AI, Sviridov DV. Transformations of mixed molybdenum – vanadium oxides in the oxidation of hydrocarbons by molecular oxygen. Russian Journal of Physical Chemistry B. 2013;7(6):734–738. DOI: 10.1134/S1990793113060080.
  23. Sviridova TV, Sadovskaya LYu, Matrosova OV, Vishnetskaya MV, Kokorin AI, Sviridov DV. Catalytic activity of MoO3 : V2O5 mixed oxides towards oxidation reactions: the nature of catalytic centers. Mendeleev Communications. 2024;34(5):715–717. DOI: 10.1016/j.mencom.2024.09.029.

Downloads

Additional Files

Published

2026-08-28

Issue

No. 1 (2026): Journal of the Belarusian State University. Chemistry

Section

Original Articles

License

Copyright (c) 2026 Journal of the Belarusian State University. Chemistry

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

The authors who are published in this journal agree to the following:

  1. The authors retain copyright on the work and provide the journal with the right of first publication of the work on condition of license Creative Commons Attribution-NonCommercial. 4.0 International (CC BY-NC 4.0).
  2. The authors retain the right to enter into certain contractual agreements relating to the non-exclusive distribution of the published version of the work (e.g. post it on the institutional repository, publication in the book), with the reference to its original publication in this journal.
  3. The authors have the right to post their work on the Internet (e.g. on the institutional store or personal website) prior to and during the review process, conducted by the journal, as this may lead to a productive discussion and a large number of references to this work. (See The Effect of Open Access.)

How to Cite

[1]
Sviridova, T.V. et al. 2026. Molybdenum – vanadium oxide solid solutions used as a tunable redox catalyst for electrochemical growing of nickel-matrix composites. Journal of the Belarusian State University. Chemistry. 1 (Aug. 2026), 61–67. DOI:https://doi.org/10.33581/2520-257X-2026-1-%p.