Improving the efficiency of an industrial silicon solar cell by doping with nickel

Authors

  • Mukhamed Kabir Bakhadirkhanov Tashkent State Technical University named after Islam Karimov, 2 University Street, Tashkent 100095, Uzbekistan
  • Zoir Toxir Kenzhaev Karakalpak State University named after Berdakh, 1 Ch. Abdirov Street, Nukus 230112, Uzbekistan
  • Bayrambay K. Ismaylov Tashkent State Technical University named after Islam Karimov, 2 University Street, Tashkent 100095, Uzbekistan
  • Vladimir B. Odzhaev Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus
  • Uladislau S. Prasalovich Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus
  • Yuri N. Yankovski Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus

Keywords:

silicon photocell, maximum power, nickel diffusion, nickel-enriched layer

Abstract

The possibility of adjusting the operational parameters of industrial solar cells produced by the company Suniva based on monocrystalline silicon by means of additional diffusion doping with nickel in the temperature range 700–1200 °C has been investigated. It is shown that the optimal temperature of nickel diffusion is Tdiff = 800–850 °C. In this case the value of the maximum power Pmax increases by 20–28 % in relation to the parameters of the original industrial photocell. At diffusion temperatures Tdiff > 1000 °C, a sharp decrease in Pmax occurs, which is associated with an increase in the depth of the pn-junction due to the distillation of phosphorus atoms during high-temperature diffusion of nickel. The positive effect of diffusion alloying with nickel on the electrophysical parameters of photocells is greatest in the case when the nickel impurity clusters are in the region of the pn-junction, i. e. with diffusion alloying to the front side of the plate. The action of electrically neutral nickel clusters is less pronounced when they are located in the region of the isotypic pp+ transition; in case of diffusion alloying with nickel in the opposite side of the plate.

Author Biographies

  • Mukhamed Kabir Bakhadirkhanov, Tashkent State Technical University named after Islam Karimov, 2 University Street, Tashkent 100095, Uzbekistan

    academician of the Academy of Sciences of the Republic of Uzbekistan, doctor of science (physics and mathematics), full professor; professor at the department of digital electronics and microelectronics, faculty of electronics and automation

  • Zoir Toxir Kenzhaev, Karakalpak State University named after Berdakh, 1 Ch. Abdirov Street, Nukus 230112, Uzbekistan

    basic doctoral student at the department of physics semiconductors, physical faculty

  • Bayrambay K. Ismaylov, Tashkent State Technical University named after Islam Karimov, 2 University Street, Tashkent 100095, Uzbekistan

    PhD (physics and mathematics); senior lecturer at the department of digital electronics and microelectronics, faculty of electronics and automation

  • Vladimir B. Odzhaev, Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus

    doctor of science (physics and mathematics), full professor; head of the department of semiconductor physics and nanoelectronics, faculty of physics

  • Uladislau S. Prasalovich, Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus

    PhD (physics and mathematics), docent; head of the laboratory of semiconductor spectroscopy, department of semiconductor physics and nanoelectronics, faculty of physics

  • Yuri N. Yankovski, Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus

    PhD (physics and mathematics); leading researcher at the laboratory of semiconductor spectroscopy, department of semiconductor physics and nanoelectronics, faculty of physics

References

  1. Gremenok VF, Tivanov MS, Zalecskii VB. Solnechnye elementy na osnove poluprovodnikovykh materialov [Solar cells based on semiconductor materials]. Minsk: Publishing Center of the Belarusian State University; 2007. 222 p. Russian.
  2. Seredin PV, Len’shin AS. [The main problems of the formation of nano- and heterostructures based on silicon and A3B5 semiconductors for modern optoelectronics]. Molodoi uchenyi. 2013;11:28–31. Russian.
  3. Brinkevich DI, Vabishchevich SA, Prosolovich VS, Yankovskii YuN. Redkozemel’nye elementy v monokristallicheskom kremnii [Rare earth elements in monocrystalline silicon]. Novopolotsk: Polotsk State University; 2003. 203 p. Russian.
  4. Bakhadirkhanov MK, Isamov SB, Kenzhaev ZT, Koveshnikov SV. Studying the effect of doping with nickel on silicon-based solar cells with a deep p–n-junction. Technical Physics Letters. 2019;45(10):959–962. DOI: 10.1134/S1063785019100031.
  5. Bakhadirkhanov MK, Isamov SB, Kenzhaev ZT, Melebaev D, Zikrillayev KhF, Ikhtiyarova GA. Silicon photovoltaic cells with deep p–n-junction. Applied Solar Energy. 2020;56(1):13–17. DOI: 10.3103/S0003701X2001003X.
  6. Bakhadirkhanov MK, Kenzhaev ZT. [Optimal conditions for nickel alloying to increase the efficiency of silicon solar cells]. Zhurnal tekhnicheskoi fiziki. 2021;91(6):981–986. Russian. DOI: 10.21883/jtf.2021.06.50868.332-20.
  7. Kalinkin IP, Kukushkin SA, Osipov AV. Effect of chemical treatment of a silicon surface on the quality and structure of siliconcarbide epitaxial films synthesized by atom substitution. Semiconductors. 2018;52(6):802–808. DOI: 10.1134/S1063782618060118.
  8. Vorob’eva TN, Kobets AV, Reva OV, Vrublevskaya ON. [Deposition of multilayer metal films from solutions on silicon]. In: Ivashkevich OA, Vorob’eva TN, Arshanskii EYa, Branitskii GA, Vasilevskaya EI, editors. Sviridovskie chteniya. Vypusk 7 [Sviridov readings. Issue 7]. Minsk: Belarusian State University; 2011. p. 34–43. Russian.
  9. Stapf A, Gondek C, Kroke E, Roewer G. Wafer cleaning, etching, and texturization. In: Yang D, editor. Handbook of photovoltaic silicon. Berlin: Springer; 2018. p. 1–47. DOI: 10.1007/978-3-662-52735-1_17-1.
  10. Lindroos J, Fenning DP, Backlund DJ, Verlage E, Gorgulla A, Estreicher SK, et al. Nickel: a very fast diffuser in silicon. Journal of Applied Physics. 2013;113(20):204906. DOI: 10.1063/1.4807799.
  11. Boltaks BI. Diffuziya i tochechnye defekty v poluprovodnikakh [Diffusion and point defects in semiconductors]. Leningrad: Nauka; 1972. 384 p. Russian.
  12. Vu Van Hung, Phan Thi Thanh Hong, Bui Van Khue. Boron and phosphorus diffusion in silicon: interstitial, vacancy and combination mechanisms. Proceedings of the National Conference on Theoretical Physics. 2010;35:73–79.
  13. Chistokhin IB, Fritsler KB. [Influence of getter formation conditions in high-resistance silicon on the characteristics of PIN photodiodes]. Pis’ma v zhurnal tekhnicheskoi fiziki. 2020;46(21):11–13. Russian. DOI: 10.21883/PJTF.2020.21.50188.18455.
  14. Bakhadirkhanov MK, Ismaylov BK. [Gettering properties of nickel atom clusters in a silicon lattice]. Pribory. 2020;6:44–48. Russian.
  15. Khvostikov VP, Sorokina SV, Khvostikova OA, Timoshina NKh, Potapovich NS, Ber BYa, et al. High efficient photocells based on GaSb. Fizika i tekhnika poluprovodnikov. 2013:47(2);273–279. Russian.
  16. Bakhadirkhanov MK, Ismaylov BK, Ismailov KA, Zikrillaev NF, Isamov SB. On how thermal annealing affects the state of clusters of nickel atoms in crystal lattice of silicon. International Journal of Advanced Science and Technology. 2020;29(9s):6308–6312.
  17. Astashenkov AS, Brinkevich DI, Petrov VV. [Properties of silicon doped with nickel admixture by diffusion]. Doklady Belorusskogo gosudarstvennogo universiteta informatiki i radioelektroniki. 2008;38(8):37–43. Russian.
  18. Panaiotti IE, Terukov EI, Shakhrai IS. [Method for calculating the performance characteristics of silicon heterojunction solar cells with arbitrary parameters of the crystal substrate]. Pis’ma v zhurnal tekhnicheskoi fiziki. 2020;46(17):3–5. Russian. DOI: 10.21883/PJTF.2020.17.49883.18377.
  19. Green M, Dunlop E, Hohl-Ebinger J, Yoshita M, Kopidakis N, Hao X. Solar cell efficiency tables (version 57). Progress in Photovoltaics: Research and Applications. 2021;29(1):3–15. DOI: 10.1002/pip.3371.
  20. Sachenko AV, Shkrebtii AI, Korkishko RM, Kostylyov VP, Kulish NR, Sokolovskyi IO. Features of phototransformation in the high-efficiency silicon solar cells. Fizika i tekhnika poluprovodnikov. 2015;49(2):271–277. Russian.
  21. Kryukov VL, Furmanov GP, Brinkevich DI, Vabishchevich NV, Prosolovich VS, Yankovskii YuN. [Properties of nickel diffusion-doped silicon]. Izvestiya vysshikh uchebnykh zavedenii. Materialy elektronnoi tekhniki. 2002;1:22–24. Russian.
  22. Vasil’ev YuB, Verezub NA, Mezhennyi MV, Prosolovich VS, Prostomolotov AI, Reznik VYa. [Features of defect formation in the process of heat treatment of dislocation-free single-crystal silicon wafers of large diameter with a given distribution in the volume of oxygen-containing gettering center]. Izvestiya vysshikh uchebnykh zavedenii. Materialy elektronnoi tekhniki. 2012;2:43–51. Russian.
  23. Dhar S, Chakrabarti S. Electroless Ni plating on n- and p-type porous Si for ohmic and rectifying contacts. Semiconductor Science and Technology. 1996;11(8):1231–1234.

Downloads

Additional Files

Published

2021-09-29

Issue

Section

Semiconductor Physics and Engineering

How to Cite

(1)
Bakhadirkhanov, M. K.; Kenzhaev, Z. T.; Ismaylov, B. K.; Odzhaev, V. B.; Prasalovich, U. S.; Yankovski, Y. N. Improving the Efficiency of an Industrial Silicon Solar Cell by Doping With Nickel. Журнал Белорусского государственного университета. Физика 2021, No. 3, 32-39. https://doi.org/10.33581/2520-2243-2021-3-4-12.