Crystal growth and f – f transition intensities analysis of praseodymium ions in yttrium-aluminum orthoborates

Authors

  • Maxim P. Demesh Belarusian National Technical University, 65 Niezaliežnasci Avenue, Minsk 220013, Belarus
  • Konstantin N. Gorbachenya Belarusian National Technical University, 65 Niezaliežnasci Avenue, Minsk 220013, Belarus
  • Viktor E. Kisel Belarusian National Technical University, 65 Niezaliežnasci Avenue, Minsk 220013, Belarus
  • Elena A. Volkova Lomonosov Moscow State University, 1 Leninskie Gory, Moscow 119991, Russia
  • Viktor V. Maltsev Lomonosov Moscow State University, 1 Leninskie Gory, Moscow 119991, Russia
  • Elizaveta V. Koporulina Lomonosov Moscow State University, 1 Leninskie Gory, Moscow 119991, Russia
  • Alexey A. Kornienko Vitebsk State University of Technology, 72 Maskoŭski Avenue, Vitebsk 210038, Belarus
  • Elena B. Dunina Vitebsk State University of Technology, 72 Maskoŭski Avenue, Vitebsk 210038, Belarus
  • Nikolay V. Kuleshov Vitebsk State University of Technology, 72 Maskoŭski Avenue, Vitebsk 210038, Belarus

Keywords:

flux growth, rare-earth aluminum borates, praseodymium, absorption, transition intensities
Supporting Agencies
This research was supported by Russian Foundation for Basic Research (project No. 18-29-12091 mk).

Abstract

A Pr3+ : YAl3(BO3)4 crystal with sizes of  20 × 10 × 10 mm was grown from high-temperature solution and its structural and spectroscopic properties were investigated. The distribution coefficient of praseodymium ranged from 0.6 to 0.8, that yield to the Pr3+ ion concentration of 1.1 ⋅1020 cm–3. Visible and infrared groundstate absorption (3H4) was measurement in dependence on the polarisation. The absorption spectra of the Pr3+ : YAl3(BO3)4 exhibit pronounced polarisation anisotropy. The modified Judd – Offelt theory was applied to evaluate the transitions intensities in absorption and emission, branching ratios and radiative lifetimes of the metastable levels 3P0 and 1D2.

Author Biographies

  • Maxim P. Demesh, Belarusian National Technical University, 65 Niezaliežnasci Avenue, Minsk 220013, Belarus

    PhD (physics and mathematics); senior researcher at the center for optical materials and technologies, faculty of instrumentation engineering

  • Konstantin N. Gorbachenya, Belarusian National Technical University, 65 Niezaliežnasci Avenue, Minsk 220013, Belarus

    PhD (physics and mathematics), docent; senior researcher at the center for optical materials and technologies, faculty of instrumentation engineering

  • Viktor E. Kisel, Belarusian National Technical University, 65 Niezaliežnasci Avenue, Minsk 220013, Belarus

    PhD (physics and mathematics), docent; head of the center for optical materials and technologies, faculty of instrumentation engineering

  • Elena A. Volkova, Lomonosov Moscow State University, 1 Leninskie Gory, Moscow 119991, Russia

    PhD (chemistry), docent; associate professor at the department of crystallography and crystal chemistry, faculty of geology

  • Viktor V. Maltsev, Lomonosov Moscow State University, 1 Leninskie Gory, Moscow 119991, Russia

    doctor of science (chemistry); senior researcher at the department of crystallography and crystal chemistry, faculty of geology

  • Elizaveta V. Koporulina, Lomonosov Moscow State University, 1 Leninskie Gory, Moscow 119991, Russia

    PhD (geology and mineralogy), docent; associate professor at the department of crystallography and crystal chemistry, faculty of geology

  • Alexey A. Kornienko, Vitebsk State University of Technology, 72 Maskoŭski Avenue, Vitebsk 210038, Belarus

    doctor of science (physics and mathematics), full professor; professor at the department of information systems and production automation, faculty of information technology and robotics

  • Elena B. Dunina, Vitebsk State University of Technology, 72 Maskoŭski Avenue, Vitebsk 210038, Belarus

    PhD (physics and mathematics), docent; associate professor at the department of information systems and production automation, faculty of information technology and robotics

  • Nikolay V. Kuleshov, Vitebsk State University of Technology, 72 Maskoŭski Avenue, Vitebsk 210038, Belarus

    doctor of science (physics and mathematics), full professor; head of the department of laser devices and technology, faculty of instrumentation engineering

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Published

2022-02-03

Issue

No. 1 (2022): Journal of the Belarusian State University. Physics

Section

Optics and Spectroscopy

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How to Cite

(1)
Demesh, M. P. .; Gorbachenya, K. N. .; Kisel, V. E. .; Volkova, E. A. .; Maltsev, V. V. .; Koporulina, E. V. .; Kornienko, A. A. .; Dunina, E. B.; Kuleshov, N. V. . Crystal Growth and F – F Transition Intensities Analysis of Praseodymium Ions in Yttrium-Aluminum Orthoborates. Журнал Белорусского государственного университета. Физика 2022, No. 1, 4-13. https://doi.org/10.33581/2520-2243-2022-1-4-13.
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