Prospects of scientific research and education in the field of physics of carbon nanomaterials in Belarusian State University

Authors

  • Igor N. Gromov Belarusian State University, 4 Niezaliezhnasci Avenue, Minsk 220030, Belarus
  • Marina I. Demidenko Institute for Nuclear Problems, Belarusian State University, 11 Babrujskaja Street, Minsk 220006, Belarus
  • Vitaly K. Ksenevich Institute for Nuclear Problems, Belarusian State University, 11 Babrujskaja Street, Minsk 220006, Belarus
  • Maria A. Samarina Belarusian State University, 4 Niezaliezhnasci Avenue, Minsk 220030, Belarus
  • Nadzeya I. Volynets Institute for Nuclear Problems, Belarusian State University, 11 Babrujskaja Street, Minsk 220006, Belarus
  • Sergey A. Maksimenko Institute for Nuclear Problems, Belarusian State University, 11 Babrujskaja Street, Minsk 220006, Belarus

Keywords:

carbon nanomaterials, chemical vapour deposition, graphene, pyrolytic carbon, diamond-like carbon, Raman spectroscopy
Supporting Agencies
The work was carried out within the framework of the state scientific and technical programme for 2021–2025 «National standards and high-tech research equipment» (subprogramme «Scientific and educational equipment », assignments 57 and 67), state scientific research programme «Convergence-2025» (subprogramme «Interdisciplinary research and new emerging technologies», assignment 3.02.2) and state scientific research programme «Materials science, new materials and technologies» (subprogramme «Nanostructure», assignment 2.14.3). The authors express their gratitude to O. V. Korolik for measuring the Raman spectra of graphene samples and pyrolytic carbon films.

Abstract

The scientific and educational laboratory complex developed by employees of the faculty of physics of Belarusian State University and the Institute for Nuclear Problems, Belarusian State University, for the synthesis of graphenelike and nanocarbon materials by chemical vapour deposition is described. It is noted that the purpose of creating this complex is to improve the educational process and material base for conducting scientific research in the field of nanomaterials and nanotechnologies in BSU. It is given a brief description of the complex that allows the synthesis of graphene on copper and nickel substrates, as well as pyrolytic carbon films with reproducible structural properties, which is confirmed by the results of sample analysis using the Raman spectroscopy. Typical Raman spectra of samples synthesised using the laboratory complex are presented. A brief description of the laboratory workshop introduced into the educational process of the faculty of physics of BSU is provided. The prospects for the development of the education and scientific research in the field of nanomaterials and nanotechnologies in the named university are discussed.

Author Biographies

  • Igor N. Gromov, Belarusian State University, 4 Niezaliezhnasci Avenue, Minsk 220030, Belarus

    junior researcher at the research laboratory of physics of electronic materials, department of semiconductor physics and nanoelectronics, faculty of physics, Belarusian State University, and junior researcher at the laboratory of nanoelectromagnetics, Institute for Nuclear Problems, Belarusian State University

  • Marina I. Demidenko, Institute for Nuclear Problems, Belarusian State University, 11 Babrujskaja Street, Minsk 220006, Belarus

    Head of the Laboratory of Nanoelectromagnetism, National Research University “Institute for Nuclear Problems”, BSU.

  • Vitaly K. Ksenevich, Institute for Nuclear Problems, Belarusian State University, 11 Babrujskaja Street, Minsk 220006, Belarus

    PhD (physics and mathematics), docent; head of the research laboratory of physics of electronic materials, department of semiconductor physics and nanoelectronics, faculty of physics

  • Maria A. Samarina, Belarusian State University, 4 Niezaliezhnasci Avenue, Minsk 220030, Belarus

    junior researcher at the research laboratory of physics of electronic materials, department of semiconductor physics and nanoelectronics, faculty of physics

  • Nadzeya I. Volynets, Institute for Nuclear Problems, Belarusian State University, 11 Babrujskaja Street, Minsk 220006, Belarus

    PhD (physics and mathematics); senior researcher at the laboratory of nanoelectromagnetics

  • Sergey A. Maksimenko, Institute for Nuclear Problems, Belarusian State University, 11 Babrujskaja Street, Minsk 220006, Belarus

    doctor of science (physics and mathematics), full professor; director

References

  1. Елецкий АВ, Искандарова ИМ, Книжник АА, Красиков ДН. Графен: методы получения и теплофизические свойства. Успехи физических наук. 2011;181(3):233–268. DOI: 10.3367/UFNr.0181.201103a.0233.
  2. Грайфер ЕД, Макотченко ВГ, Назаров АС, Ким СДж, Федоров ВЕ. Графен: химические подходы к синтезу и модифицированию. Успехи химии. 2011;80(8):784–804. DOI: 10.1070/RC2011v080n08ABEH004181.
  3. Dresselhaus MS, Dresselhaus G, Eklund PC. Science of fullerenes and carbon nanotubes. Journal of the American Chemical Society. 1996;118(37):8987. DOI: 10.1021/ja965593l.
  4. Dresselhaus MS, Dresselhaus G, Avouris Ph, editors. Carbon nanotubes: synthesis, structure, properties, and applications. Heidelberg: Springer; 2003. 449 p. (Topics in applied physics; volume 80). DOI: 10.1007/3-540-39947-X.
  5. Bokros JC. Deposition, structure and properties of pyrolytic carbon. In: Walker PL, editor. Chemistry and physics of carbon. Volume 4. New York: Marcel Dekker Inc.; 1969. p. 1–118.
  6. McEvoy N, Peltekis N, Kumar Sh, Rezvani E, Nolan H, Keeley GP, et al. Synthesis and analysis of thin conducting pyrolytic carbon films. Carbon. 2012;50(3):1216–1226. DOI: 10.1016/j.carbon.2011.10.036.
  7. Maffucci A, Maksimenko S, Svirko Yu, editors. Carbon-based nanoelectromagnetics. Amsterdam: Elsevier; 2019. 258 p. (Nanophotonics).
  8. Шашкова ЕГ, Волынец НИ, Демиденко МИ, Поддубская ОГ. Электромагнитные свойства пористых 3D-структур на основе углерода в высокочастотном диапазоне. Известия высших учебных заведений. Физика. 2021;64(6):76–83. DOI: 10.17223/00213411/64/6/68.
  9. Максименко СА, Кулагова ТА, Окотруб АВ, Сусляев ВИ. Актуальные задачи использования композиционных и гибридных материалов на основе различных форм углерода в электромагнитных и биомедицинских приложениях. Журнал Белорусского государственного университета. Физика. 2023;1:55–69.
  10. More RB, Haubold AD, Bokros JC. Pyrolytic carbon for long-term medical implants. In: Ratner BD, Hoffman AS, Schoen FJ, Lemons JE. Biomaterials science. Amsterdam: Academic Press; 2013. p. 209–222. DOI: 10.1016/B978-0-08-087780-8.00023-1.
  11. Batrakov K, Kuzhir P, Maksimenko S, Paddubskaya A, Voronovich S, Kaplas T, et al. Enhanced microwave shielding effectiveness of ultrathin pyrolytic carbon films. Applied Physics Letters. 2013;103:073117. DOI: 10.1063/1.48186802013.
  12. Batrakov K, Kuzhir P, Maksimenko S, Paddubskaya A, Voronovich S, Lambin Ph, et al. Flexible transparent graphene/polymer multilayers for efficient electromagnetic field absorption. Scientific Reports. 2014;4(1):7191. DOI: 10.1038/srep07191.
  13. Демиденко МИ, Адамчук ДВ, Русанов АП, Сироткин СВ, Иванько ЛВ, Максименко СА. Легированный бором пиролитический углерод: материал для биомедицинского и инженерно-технического применения. Доклады Национальной академии наук Беларуси. 2023;67(3):250–256. DOI: 10.29235/1561-8323-2023-67-3-250-256.
  14. Demidenko M, Adamchuk Dz, Liubimau A, Uglov V, Ishchenko A, Chekan M, et al. High temperature synthesis and material properties of boron-enriched balk pyrolytic carbon. Materials Science and Engineering B. 2024;307:117491. DOI: 10.1016/j.mseb.2024.117491.
  15. Федотов АК, Харченко АА, Гуменник ВЭ, Федотова ЮА, Чичков МВ, Малинкович ВД и др. Влияние синтеза и подложки на электросопротивление в однослойном графене. В: Оджаев ВБ, редактор. Материалы и структуры современной электроники. Материалы IX Международной научной конференции; 14–16 октября 2020 г.; Минск, Беларусь. Минск: БГУ; 2020. с. 420–424. EDN: UVCYTQ.
  16. Колесов ЕА, Тиванов МС, Королик ОВ, Свито ИА, Антонович АС, Капитанова ОО, et al. Влияние отжига на фононные и электронные свойства графена на SiO2/Si и Al2O3. В: Оджаев ВБ, редактор. Материалы и структуры современной электроники. Материалы X Международной научной конференции; 12–14 октября 2022 г.; Минск, Беларусь. Минск: БГУ; 2022. с. 423–430.
  17. Тиванов МС, Колесов ЕА, Королик ОВ, Саад АМ, Ковальчук НГ, Комиссаров ИВ и др. Спектры комбинационного рассеяния света графена, синтезированного методом химического осаждения из газовой фазы с использованием декана. Журнал прикладной спектроскопии. 2017;84(6):898–904. EDN: ZTSSOZ.
  18. Kuzhir PP, Poddubskaya OG, Bychenok DS, Pliyushch A, Nemilentsau A, Shuba MV, et al. CNT based epoxy resin composites for conductive applications. Nanoscience and Nanotechnology Letters. 2011;3(6):889–894. DOI: 10.1166/nnl.2011.1252.
  19. Seliuta D, Kašalynas I, Macutkevic J, Valušis G, Shuba MV, Kuzhir PP, et al. Terahertz sensing with carbon nanotube layers coated on silica fibers: carrier transport versus nanoantenna effects. Applied Physics Letters. 2010;97(7):073116. DOI: 10.1063/1.3478009.
  20. Grill A. Diamond-like carbon: state of the art. Diamond and Related Materials. 1999;8:428–434. DOI: 10.1016/S0925-9635(98)00262-3.
  21. Боровиков СМ, Пигаль РВ, Терещук ОИ. Свойства и применение DLC-покрытий. Молодой ученый. 2021;6:6–9. EDN: IKXSNR.
  22. Седельникова ОВ, Городецкий ДВ, Федоренко АД, Баскакова КИ, Поддубская ОГ, Королик ОВ и др. Влияние sp2-гибридизированных углеродных включений в алмазной пленке на сенсорные свойства по отношению к синхротронному излучению. Журнал структурной химии. 2024;65(9):132222. DOI: 10.26902/jsc_id132222.
  23. Dhingra Sh, Hsu JF, Vlassiouk I, D’Urso B. Chemical vapor deposition of graphene on large-domain ultra-flat copper. Carbon. 2014;69:188–193. DOI: 10.1016/j.carbon.2013.12.014.
  24. Смовж ДВ, Костогруд ИА, Бойко ЕВ, Маточкин ПЕ, Безруков ИА, Кривенко АС. Синтез графена методом химического осаждения из газовой фазы и его перенос на полимер. Прикладная механика и техническая физика. 2020;61(5):235–245. DOI: 10.15372/PMTF20200524.
  25. Losurdo M, Giangregorio MM, Capezzuto P, Bruno G. Graphene CVD growth on copper and nickel: role of hydrogen in kinetics and structure. Physical Chemistry Chemical Physics. 2011;13(46):20836–20843. DOI: 10.1039/c1cp22347j.
  26. Wang Q, Wei L, Sullivan M, Yangb SW, Chen Yu. Graphene layers on Cu and Ni(111) surfaces in layer controlled graphene growth. RSC Advances. 2013;3(9):3046–3053. DOI: 10.1039/c2ra23105k.
  27. Her M, Beams R, Novotny L. Graphene transfer with reduced residue. Physics Letters A. 2013;377(21–22):1455–1458. DOI: 10.1016/j.physleta.2013.04.015.
  28. Kaplas T, Svirko YuP. Direct deposition of semitransparent conducting pyrolytic carbon films. Journal of Nanophotonics. 2012;6(1):061703. DOI: 10.1117/1.jnp.6.061703.
  29. Kaplas T, Svirko Y, Kuzhir P. Synthesis of pyrolytic carbon films on dielectric substrates. In: Maffucci A, Maksimenko SA, editors. Fundamental and applied nano-electromagnetics. Dordrecht: Springer; 2016. p. 227–238 (NATO science for peace and security. Series B, Physics and biophysics). DOI: 10.1007/978-94-017-7478-9_12.
  30. Malard LM, Pimenta MA, Dresselhaus G, Dresselhaus MS. Raman spectroscopy in graphene. Physics Reports. 2009;473(5–6):51–87. DOI: 10.1016/j.physrep.2009.02.003.
  31. Li Zh, Deng L, Kinloch IAA, Young RJ. Raman spectroscopy of carbon materials and their composites: graphene, nanotubes and fibres. Progress in Materials Science. 2023;135:101089. DOI: 10.1016/j.pmatsci.2023.101089.
  32. Nanda SS, Kim MJ, Yeom KS, An SSA, Ju H, Yi DK. Raman spectrum of graphene with its versatile future perspectives. TrAC Trends in Analytical Chemistry. 2016;80:125–131. DOI: 10.1016/j.trac.2016.02.024.
  33. Конакова РВ, Коломыс АФ, Охрименко ОБ, Стрельчук ВВ, Волков ЕЮ, Григорьев МН и др. Сравнительные характеристики спектров комбинационного рассеяния света пленок графена на проводящих и полуизолирующих подложках 6H-SiC. Физика и техника полупроводников. 2013;47(6):802–804.
  34. Zhao L, He R, Rim KT, Schiros Th, Kim KS, Zhou H, et al. Visualizing individual nitrogen dopants in monolayer graphene. Science. 2011;333:999–1003. DOI: 10.1126/science.1208759.
  35. Lherbier A, Blase X, Niquet YaM, Triozon F, Roche S. Charge transport in chemically doped 2D graphene. Physical Review Letters. 2008;101:036808. DOI: 10.1103/PhysRevLett.101.036808.
  36. Wang H, Maiyalagan T, Wang X. Review on recent progress in nitrogen-doped graphene: synthesis, characterization, and its potential applications. ACS Catalysis. 2012;2(5):781–794. DOI: 10.1021/cs200652y.
  37. Agnoli S, Favaro M. Doping graphene with boron: a review of synthesis methods, physicochemical characterization, and emerging applications. Journal of Materials Chemistry A. 2016;4(14):5002–5025. DOI: 10.1039/C5TA10599D.
  38. Luo Zh, Lim S, Tian Zh, Shang J, Lai L, MacDonald B, et al. Pyridinic N doped graphene: synthesis, electronic structure, and electrocatalytic property. Journal of Materials Chemistry. 2011;21(22):8038–8044. DOI: 10.1039/c1jm10845j.
  39. Макеева ГС, Голованов ОА, Вареница ВВ, Артамонов ДВ. Математическое моделирование прохождения терагерцевого излучения через монослой графена. Известия высших учебных заведений. Поволжский регион. Физико-математические науки. 2014;3:145–158. EDN: RBYEKA.
  40. Batrakov K, Kuzhir P, Maksimenko S, Volynets N, Voronovich S, Paddubskaya A, et al. Enhanced microwave-to-terahertz absorption in graphene. Applied Physics Letters. 2016;108(12):123101. DOI: 10.1063/1.4944531.
  41. Maffucci A, Maksimenko SA, editors. Fundamental and applied nano-electromagnetics II: THz circuits, materials, devices. Dordrecht: Springer; 2019. 290 p. (NATO science for peace and security. Series B, Physics and biophysics). DOI: 10.1007/978-94-024-1687-9.
  42. Baah M, Paddubskaya A, Novitsky A, Valynets N, Kumar M, Itkonen T, et al. All-graphene perfect broadband THz absorber. Carbon. 2021;185:709–716. DOI: 10.1016/j.carbon.2021.09.067.
  43. Lamberti P, La Mura M, Tucci V, Nkyalu E, Khan A, Yakovleva M, et al. The performance of graphene-enhanced THz grating: impact of the gold layer imperfectness. Materials. 2022;15(3):786. DOI: 10.3390/ma15030786.
  44. Batrakov KG, Valynets NI, Dubinetski MM, Paddubskaya AG, Margaryan HL, Hakobyan NH, et al. Fabry-Perot enhancement of liquid crystals birefringence effects in terahertz range. Physica Scripta. 2024;100(1):0155120. DOI: 10.1088/1402-4896/ad96e8.

Downloads

Published

2025-11-04

Issue

Section

Nanomaterials and Nanotechnologies

How to Cite

(1)
Gromov, I. N.; Demidenko, M. I.; Ksenevich, V. K.; Samarina, M. A.; Volynets, N. I.; Maksimenko, S. A. Prospects of Scientific Research and Education in the Field of Physics of Carbon Nanomaterials in Belarusian State University. Журнал Белорусского государственного университета. Физика 2025, No. 2, 74-84.