Application of surfactants for the synthesis of qualitative hydroxide and metallic cobalt nanopowders

Authors

  • Van Minh Nguyen Institute of Technology, 3 Cau Vong Street, Hanoi 100000, Vietnam
  • Tien Hiep Nguyen Le Quy Don Technical University, 236 Hoang Quoc Viet Street, Hanoi 100000, Vietnam https://orcid.org/0000-0002-3023-556X
  • Stanislav V. Gorobinsky National University of Science and Technology «MISiS», 4 Leninsky Avenue, Moscow 119049, Russia

Keywords:

nanopowder, cobalt, cobalt hydroxide, chemical precipitation, surfactant

Abstract

In this work, nanopowders (NP) Co(OH)2 were obtained by chemical precipitation from aqueous solutions of cobalt nitrate Co(NO3)2 and alkali NaOH (10 wt. %) using surfactants: sodium dodecyl sulfate (SDS) and cetylpyridinium chloride (CPC) (0.1 wt. %). It was shown that Co(OH)2 NP with 0.1% SDS is the best quality product, since its dispersion increases more than 2 times compared to the samples with 0.1% CPC and without surfactants. In this case, the Co(OH)2 NP has the form of flakes with an irregular shape and a nanometer size (about 100 nm) with an average thickness of 30 nm. It was found that the average particle size of Co NP obtained by hydrogen reduction of Co(OH)2 NP with 0.1% SDS at 280°C has a maximum on the distribution histogram shifted to the interval 41–50 nm, which is characterized by a narrow particle size distribution and represents spherical particles sintered with each other.

Author Biographies

  • Van Minh Nguyen, Institute of Technology, 3 Cau Vong Street, Hanoi 100000, Vietnam

    PhD (engineering); researcher at the department of materials technology

  • Tien Hiep Nguyen, Le Quy Don Technical University, 236 Hoang Quoc Viet Street, Hanoi 100000, Vietnam

    lecturer at the department of materials science and engineering, faculty of mechanical engineering

  • Stanislav V. Gorobinsky, National University of Science and Technology «MISiS», 4 Leninsky Avenue, Moscow 119049, Russia

    physical engineer at the department of functional nanosystems and high-temperature materials, College of New Materials and Nanotechnologies

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Published

2021-02-09

Issue

No. 1 (2021): Journal of the Belarusian State University. Physics

Section

Nanomaterials and Nanotechnologies

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How to Cite

(1)
Nguyen, V. M. .; Nguyen, T. H.; Gorobinsky, S. V. . Application of Surfactants for the Synthesis of Qualitative Hydroxide and Metallic Cobalt Nanopowders. Журнал Белорусского государственного университета. Физика 2021, No. 1, 4-11. https://doi.org/10.33581/2520-2243-2021-1-4-11.
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