Copper(II) complexes with 1-methyltetrazole: new method for synthesis and properties

  • Andrey N. Bogatikov Belarusian State University, Nezavisimosti avenue, 4, 220030, Minsk
  • Mikhail M. Degtyarik Research Institute for Physical Chemical Problems of Belarusian State University, Leningradskaya street, 14, 220006, Minsk
  • Oleg A. Ivashkevich Belarusian State University, Nezavisimosti avenue, 4, 220030, Minsk

Abstract

A new approach for synthesis of copper(II) complexes with 1-methyltetrazole based on oxidative dissolution of metallic powdercopper in ethanol – HCl (ammonium thiocyanate) was developed. Composition and structure of the complexes prepared were studied by elemental analysis, X-ray diffraction and infrared spectroscopy in the middle (4000–400 cm–1)  and long wave (400–50 cm–1) field. In all complexes ligand shows monodentate coordination. Polymeric structure of complexes studied is formed due to bridging coordination of anions. Magnetochemical studies revealed that copper(II) chloride complexes a low-temperature ferromagnetic.

Author Biographies

Andrey N. Bogatikov, Belarusian State University, Nezavisimosti avenue, 4, 220030, Minsk

associate professor at the department of general chemistry and methods of teaching chemistry, faculty of chemistry

Mikhail M. Degtyarik, Research Institute for Physical Chemical Problems of Belarusian State University, Leningradskaya street, 14, 220006, Minsk

PhD (chemistry); leading researcher at the laboratory for chemistry of condensed systems

Oleg A. Ivashkevich, Belarusian State University, Nezavisimosti avenue, 4, 220030, Minsk

academician of the National Academy of Sciences of Belarus, doctor of science (chemistry), full professor; first vice-principal

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Published
2017-11-29
Keywords: monosubstituted tetrazole, complex compounds, direct synthesis, X-ray diffraction, IR-spectroscopy, magnetochemistry
Supporting Agencies This work was performed in framework of Topical Plan for Research and International Cooperation of Joint Institute for Nuclear Research (JINR, Dubna), Research Institute for Nuclear Problems of Belarusian State University and Research Institute for Physical Chemical Problems of Belarusian State University (Minsk) (contract number 08/88–16).
How to Cite
Bogatikov, A. N., Degtyarik, M. M., & Ivashkevich, O. A. (2017). Copper(II) complexes with 1-methyltetrazole: new method for synthesis and properties. Journal of the Belarusian State University. Chemistry, 1, 50-57. Retrieved from https://journals.bsu.by/index.php/chemistry/article/view/1157
Issue
No 1 (2017): Journal of the Belarusian State University. Chemistry
Section
Original Articles

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