Research of the adsorption of a methylene blue enterosorbents of various nature
Abstract
The results of the adsorption study of methylene blue dye as the low molecular weight toxins marker from its aqueous solutions by carbon, silicon and polymer enterosorbents are presented. It has been shown that the activated carbons modification by water-soluble cellulose polyelectrolyte makes it possible to increase their adsorption capacity. The applicability of Langmuir, Freundlich, Temkin and Redlich – Peterson adsorption models for the approximation of experimental adsorption isotherms of methylene blue on the enterosorbents has been estimated. It has been established that the three-parameter Redlich – Peterson equation describes this process better than others. This was evident from the comparison of the regression coefficients, constants and parameters values of these equations.
References
- Kormishina AE, Mizina PG, Solov’eva IL. Pharmaceutical market of medicines of adsorptive action: state and prospects. Meditsinskii vestnik Bashkortostana. 2018;13(6):55–62. Russian.
- Rachkovskaya LN, Letyagin AY, Burmistrov VA, Korolev MA, Gelfond NE, Borodin YI, et al. Modified sorbents for practical public health. Sibirskii nauchnyi meditsinskii zhurnal. 2015;35(2):47–54. Russian.
- The International Pharmacopoeia. Seventh Edition, 2017 [Internet; cited by 2020 May 23]. Available from: http://apps.who.int/phint/2017/index.html#d/b.1.
- United States Pharmacopeial Convention, The United States Pharmacopeia (USP38 – NF33). Rockville: United States Pharmacopeial Convention; [2015]. 5612 p.
- The Ministry of Health, Labour and Welfare. Japanese Pharmacopeia 17th edition. [S. l.]: The Ministry of Health, Labour and Welfare; 2016. 2643 p.
- Veprikova EV, Ivanov IP, Chesnokov NV, Kuznetsov BN. Effect of a porous structure of the carbon sorbents from abies wood lignin on sorption of the organic substances of different nature. Journal of Siberian Federal University. Chemistry. 2018;11(4):488–499. Russian. DOI: 10.17516/1998-2836-0093.
- Nevar TN, Savitskaya TA, Osipova AV, Makarevich SE, Tsygankova NG, Grinshpan DD. Colloidal-chemical properties and therapeutic activity of activated charcoal. Khimiko-farmatsevticheskii zhurnal. 2007;41(6):44–48. Russian.
- Nikolaev VG, Gerashchenko II, Kartel’ NT, Gurina NM, Bakalinskaya ON, Sarnatskaya VV, et al. Pre-clinical examenation of enterosorbents: chemopharmacentic aspect. Poverkhnost’. 2011;3(18):310–319. Russian.
- Balykin VP, Efremova OA, Bulatov AV. [Adsorption of methylene blue and methanyl yellow on a carbon surface]. Vestnik Chelyabinskogo gosudarstvennogo universiteta. 2004;4(1):46–57. Russian.
- Langmuir I. The constitution and fundamental properties of solids and liquids. Part I. Solids. Journal of the American Chemical Society. 1916;38(11):2221–2295. DOI: 10.1021/ja02268a002.
- Freundlich HMF. Over the adsorption in solution. The Journal of Physical Chemistry. 1906;57:385–471.
- Temkin MI. [Mixtures of molten salts as ionic solutions]. Zhurnal fizicheskoi khimii. 1946;20(1):105–110. Russian.
- Redlich O, Peterson DL. Useful adsorption isotherm. The Journal of Physical Chemistry. 1959;63(6):1024. DOI: 10.1021/j150576a611.
- Giner-Casares JJ, Brezesinski G, Möhwald H. Langmuir monolayers as unique physical models. Current Opinion in Colloid & Interface Science. 2014;19(3):176–182. DOI: 10.1016/j.cocis.2013.07.006.
- Giles CH. History and use of the freundlich adsorption isotherm. Journal of the Society of Dyers and Colourists. 1973;89(8):287–291. DOI: 10.1111/j.1478-4408.1973.tb03158.x.
- Kumar KV, Gadipelli S, Wood B, Ramisetty KA, Stewart AA, Howard CA, et al. Characterization of the adsorption site energies and heterogeneous surfaces of porous materials. Journal of Materials Chemistry A. 2019;7:10104–10137. DOI: 10.1039/C9TA00287A.
- Hamdaoui O, Naffrechoux E. Modeling of adsorption isotherms of phenol and chlorophenols onto granular activated carbon. Part I. Two-parameter models and equations allowing determination of thermodynamic parameters. Journal of Hazardous Materials. 2007;147(1–2):381–394. DOI: 10.1016/j.jhazmat.2007.01.021.
- Feng-Chin Wu, Bing-Lan Liu, Keng-Tung Wu, Ru-Ling Tseng. A new linear form analysis of Redlich – Peterson isotherm equation for the adsorptions of dyes. Chemical Engineering Journal. 2010;162(1):21–27. DOI: 10.1016/j.cej.2010.03.006.
- Nevar TN. Kolloidno-khimicheskie svoistva suspenzii aktivirovannykh uglei, modifitsirovannykh vodorastvorimymi polimerami [Colloidal-chemical properties of suspensions of activated carbons modified with water-soluble polymers] [dissertation]. Minsk: Belarusian State University; 2007. 139 p. Russian.
- Giles CH, Smith D, Huitson A. A general treatment and classification of the solute adsorption isotherm. I. Theoretical. Journal of Colloid and Interface Science. 1974;47(3):755–765. DOI: 10.1016/0021-9797(74)90252-5.
- Bondarev AV, Zhilyakova ET, Demina NB, Novikov VY. Study of morphology of sorption substances. Drug development & registration. 2019;8(2):33–37. Russian. DOI: 10.33380/2305-2066-2019-8-2-33-37.
- Alaya MN, Hourieh MA, Youssef AM, El-Sejariah F. Adsorption properties of activated carbons prepared from olive stones by chemical and physical activation. Adsorption Science & Technology. 2000;18(1):27–42. DOI: 10.1260/0263617001493251.
- Sobgaida NA, Ol’shanskaya LN, Makarova YA. [Influence of modification of wheat husks on its sorption properties to Pb2+, Cd2+, Zn2+ and Cu2+ ions]. Izvestiya vysshikh uchebnykh zavedenii. Khimiya i khimicheskaya tekhnologiya. 2010;53(11):36–40. Russian.
- Rychkova SA. Fiziko-khimicheskie zakonomernosti sorbtsii polyarnykh organicheskikh soedinenii razlichnykh klassov na poristom mikrodispersnom detonatsionnom nanoalmaze [Physical-chemical regularities of sorption of polar organic compounds of various classes on porous microdispersed detonation nanodiamond] [dissertation]. Moscow: Lomonosov Moscow State University; 2016. 256 p. Russian.
- Nayanova EV, Elipasheva EV, Sergeev GM, Sergeeva VP. Redox properties of methylene blue as a promising photometric reagent for determination of halogen oxidants. Analytics and Control. 2015;19(2):154–160. Russian. DOI: 10.15826/analitika. 2015.19.2.005.
- Samiey B, Ashoori F. Adsorptive removal of methylene blue by agar: effects of NaCl and ethanol. Chemistry Central Journal. 2012;6:14. DOI: 10.1186/1752-153X-6-14.
Copyright (c) 2021 Journal of the Belarusian State University. Chemistry
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
The authors who are published in this journal agree to the following:
- The authors retain copyright on the work and provide the journal with the right of first publication of the work on condition of license Creative Commons Attribution-NonCommercial. 4.0 International (CC BY-NC 4.0).
- The authors retain the right to enter into certain contractual agreements relating to the non-exclusive distribution of the published version of the work (e.g. post it on the institutional repository, publication in the book), with the reference to its original publication in this journal.
- The authors have the right to post their work on the Internet (e.g. on the institutional store or personal website) prior to and during the review process, conducted by the journal, as this may lead to a productive discussion and a large number of references to this work. (See The Effect of Open Access.)