IR spectral assay of the vanadium(III) ketiminate and vanadium(III) and vanadyl acetylacetonates

  • Nikolai N. Kostyuk Belarusian State University, 4 Niezaliezhnasci Avenue, Minsk 220030, Belarus
  • Tatiana A. Dick Belarusian State University, 4 Niezaliezhnasci Avenue, Minsk 220030, Belarus
  • Alexander R. Tsyhanau Belarusian State Technological University, 13a Sviardlova Street, Minsk 220006, Belarus

Abstract

Vanadium(III) ketiminate [V(CH3C(N)C(H)C(O)CH3)3], vanadium(III) acetylacetonate [V(CH3C(O)C(H)C(O)CH3)3] and vanadyl acetylacetonate [VO(CH3C(O)C(H)C(O)CH3)2] were obtained by electrochemical synthesis. Based on IR spectroscopy data, it was established that as a result of electrolysis, the formation of a quasi-aromatic metallocycle, the main structural element of the chelate, took place. The peripheral methyl groups of ketiminate and acetylacetone did not undergo transformation under the influence of electric current.

Author Biographies

Nikolai N. Kostyuk, Belarusian State University, 4 Niezaliezhnasci Avenue, Minsk 220030, Belarus

PhD (chemistry); leading researcher at the laboratory of applied mechanics, department of theoretical and applied mechanics, faculty of mechanics and mathematics

Tatiana A. Dick, Belarusian State University, 4 Niezaliezhnasci Avenue, Minsk 220030, Belarus

doctor of science (physics and mathematics); leading specialist at the dean’s office of the faculty of mechanics and mathematics

Alexander R. Tsyhanau, Belarusian State Technological University, 13a Sviardlova Street, Minsk 220006, Belarus

doctor of science (agricultural science), PhD (chemistry), academician of the National Academy of Sciences of Belarus, full professor; professor at the department of physical, colloidal and analytical chemistry, faculty of organic substances technology

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Published
2024-08-16
Keywords: acetylacetone, vanadium(III) ketiminate, vanadium(III) acetylacetonate, vanadyl acetylacetonate, chelate, IR spectrum, absorption band
How to Cite
Kostyuk, N. N., Dick, T. A., & Tsyhanau, A. R. (2024). IR spectral assay of the vanadium(III) ketiminate and vanadium(III) and vanadyl acetylacetonates. Journal of the Belarusian State University. Chemistry, 2, 61-69. Retrieved from https://journals.bsu.by/index.php/chemistry/article/view/6307
Issue
No 2 (2024): Journal of the Belarusian State University. Chemistry
Section
Original Articles

Copyright (c) 2024 Journal of the Belarusian State University. Chemistry

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