Electromagnetic properties of a composite medium comprising chains of tunnel-coupled carbon nanotubes
Keywords:
carbon nanotube, composite medium, tunnel coupling, permittivity, gigahertz frequency rangeAbstract
When creating a model of a composite medium based on carbon nanotubes in the gigahertz and subterahertz ranges, it is necessary to take into account the tunnel coupling between nanoparticles. To simplify the consideration, we present a model of a composite medium consisting of the same randomly oriented linear chains of parallel single walled metallic carbon nanotubes connected by tunnel contacts. The problem of scattering of electromagnetic radiation by the chains was solved through the application of the integral equation technique of classical electrodynamics and the Landauer – Buttiker formalism for quantum transport. It is shown that electron tunnelling between the nanotubes leads to the electromagnetic size effects in chains of finite length. In this case, in the gigahertz frequency range, there is a regime in which the comparable in magnitude real and imaginary parts of the effective permittivity of the composite medium decrease with increasing frequency that is often observed in experiments. It has been found that size effects can manifest themselves within small sections of the chain limited by contacts of low conductivity. The obtained results provide an understanding of the physical mechanisms responsible for the frequency dispersion of the permittivity of composite materials based on carbon nanotubes.
References
- Yonglai Yang, Gupta MC, Dudley KL. Towards cost-efficient EMI shielding materials using carbon nanostructure-based nanocomposites. Nanotechnology. 2007;18(34):345701. DOI: 10.1088/0957-4484/18/34/345701.
- Ning Li, Yi Huang, Feng Du, Xiaobo He, Xiao Lin, Hongjun Gao, et al. Electromagnetic interference (EMI) shielding of single walled carbon nanotube epoxy composites. Nano Letters. 2006;6(6):1141–1145. DOI: 10.1021/nl0602589.
- Park SH, Thielemann P, Asbeck P, Bandaru PR. Enhanced dielectric constants and shielding effectiveness of, uniformly dispersed, functionalized carbon nanotube composites. Applied Physics Letters. 2009;94(24):243111. DOI: 10.1063/1.3156032.
- Bao WS, Meguid SA, Zhu ZH, Pan Y, Weng GJ. Effect of carbon nanotube geometry upon tunneling assisted electrical network in nanocomposites. Journal of Applied Physics. 2013;113(23):234313. DOI: 10.1063/1.4809767.
- Weibang Lu, Tsu-Wei Chou, Thostenson ET. A three-dimensional model of electrical percolation thresholds in carbon nano tube-based composites. Applied Physics Letters. 2010;96(22):223106. DOI: 10.1063/1.3443731.
- Isichenko MB. Percolation, statistical topography, and transport in random media. Reviews of Modern Physics. 1992;64(4): 961–1043. DOI: 10.1103/RevModPhys.64.961.
- Sandler JKW, Kirk JE, Kinloch IA, Shaffer MSP, Windle AH. Ultra-low electrical percolation threshold in carbon-nanotube-epoxy composites. Polymer. 2003;44(19):5893–5899. DOI: 10.1016/S0032-3861(03)00539-1.
- Fuhrer MS, Nygård J, Shih L, Forero M, Young-Gui Yoon, Mazzoni MSC, et al. Crossed nanotube junctions. Science. 2000; 288(5465):494–497. DOI: 10.1126/science.288.5465.494.
- Zhen Yao, Postma HWC, Balents L, Dekker C. Carbon nanotube intramolecular junctions. Nature. 1999;402(6759):273–276. DOI: 10.1038/46241.
- Slepyan GYa, Shuba MV, Maksimenko SA, Thomsen C, Lakhtakia A. Terahertz conductivity peak in composite materials containing carbon nanotubes: theory and interpretation of experiment. Physical Review B. 2010;81(20):205423. DOI: 10.1103/Phys RevB.81.205423.
- Shuba MV, Paddubskaya AG, Plyushch AO, Kuzhir PP, Slepyan GYa, Maksimenko SA, et al. Experimental evidence of localized plasmon resonance in composite materials containing single-wall carbon nanotubes. Physical Review B. 2012;85(16):165435. DOI: 10.1103/PhysRevB.85.165435.
- Shuba MV, Paddubskaya AG, Kuzhir PP, Maksimenko SA, Flahaut E, Fierro V, et al. Short-length carbon nanotubes as building blocks for high dielectric constant materials in the terahertz range. Journal of Physics D: Applied Physics. 2017;50(8):08LT01. DOI: 10.1088/1361-6463/aa5628.
- Shuba MV, Melnikov AV, Kuzhir PP, Maksimenko SA, Slepyan GY, Boag A, et al. Integral equation technique for scatterers with mesoscopic insertions: application to a carbon nanotube. Physical Review B. 2017;96(20):205414. DOI: 10.1103/PhysRevB.96.205414.
- Slepyan GYa, Maksimenko SA, Lakhtakia A, Yevtushenko O, Gusakov AV. Electrodynamics of carbon nanotubes: dynamic conductivity, impedance boundary conditions, and surface wave propagation. Physical Review B. 1999;60(24):17136–17149. DOI: 10.1103/PhysRevB.60.17136.
- Kamenev A, Kohn W. Landauer conductance without two chemical potentials. Physical Review B. 2001;63(15):155304. DOI: 10.1103/PhysRevB.63.155304.
- Büttiker M, Imry Y, Landauer R, Pinhas S. Generalized many-channel conductance formula with application to small rings. Physical Review B. 1985;31(10):6207–6215. DOI: 10.1103/PhysRevB.31.6207.
- OdintsovAA, Tokura Y. Contact phenomena in carbon nanotubes. Physica B: Condensed Matter. 2000;284–288(part 2):1752–1753. DOI: 10.1016/S0921-4526(99)02920-8.
- Büttiker M, Prêtre A, Thomas H. Dynamic conductance and the scattering matrix of small conductors. Physical Review Letters. 1993;70(26):4114–4117. DOI: 10.1103/PhysRevLett.70.4114.
- Christen T, Büttiker M. Low frequency admittance of a quantum point contact. Physical Review Letters. 1996;77(1):143–146. DOI: 10.1103/PhysRevLett.77.143.
- Slepyan GYa, Shuba MV, Maksimenko SA, Lakhtakia A. Theory of optical scattering by achiral carbon nanotubes and their potential as optical nanoantennas. Physical Review B. 2006;73(19):195416. DOI: 10.1103/PhysRevB.73.195416.
- Melnikov AV, Kuzhir PP, Maksimenko SA, Slepyan GY, Boag A, Pulci O, et al. Scattering of electromagnetic waves by two crossing metallic single-walled carbon nanotubes of finite length. Physical Review B. 2021;103(7):075438. DOI: 10.1103/PhysRevB. 103.075438.
- Shuba MV, Melnikov AV, Paddubskaya AG, Kuzhir PP, Maksimenko SA, Thomsen C. Role of finite-size effects in the microwave and subterahertz electromagnetic response of a multiwall carbon-nanotube-based composite: theory and interpretation of experiments. Physical Review B. 2013;88(4):045436. DOI: 10.1103/PhysRevB.88.045436.
- Shuba M, Yuko D, Bychanok D, Liubimau A, Meisak D, Bochkov I, et al. Comparison of the electrical conductivity of polymer composites in the microwave and terahertz frequency ranges. In: 2017 IEEE International conference on microwaves, antennas, communications and electronic systems (COMCAS); 2017 November 13–15; Tel Aviv, Israel. [S. l.]: IEEE; 2017. p. 616–618. DOI: 10.1109/COMCAS.2017.8244754.
- Changshu Xiang, Yubai Pan, Jingkun Guo. Electromagnetic interference shielding effectiveness of multiwalled carbon nanotube reinforced fused silica composites. Ceramics International. 2007;33(7):1293–1297. DOI: 10.1016/j.ceramint.2006.05.001.
- Grimes CA, Mungle C, Kouzoudis D, Fang S, Eklund PC. The 500 MHz to 5.50 GHz complex permittivity spectra of single-wall carbon nanotube-loaded polymer composites. Chemical Physics Letters. 2000;319(5–6):460–464. DOI: 10.1016/S0009-2614(00)00196-2.
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