Re-emitting oxide – copper iodide(I) films for silicone solar cells

  • Gvidona P. Shevchenko Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus
  • Yuliya V. Bokshyts Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus https://orcid.org/0000-0001-5786-8845
  • Catherine A. Kovel Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus
  • Nadzeya V. Shynkevich Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus
  • Alexander V. Mazanik Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus
  • Dormidont A. Serban Institute of Applied Physics, 5 Academiei Street, Chisinau, MD-2028, Moldova
  • Nicolai N. Curmei Institute of Applied Physics, 5 Academiei Street, Chisinau, MD-2028, Moldova
  • Leonid I. Bruk Institute of Applied Physics, 5 Academiei Street, Chisinau, MD-2028, Moldova
  • Piotr P. Pershukevich B. I. Stepanov Institute of Physics, National Academy of Sciences of Belarus, 68-2 Niezaliežnasci Avenue, Minsk 220072, Belarus

Abstract

The effect of Al2O3 – CuI oxide films on the photoelectric parameters of silicon solar cells (SCs) has been studied. The largest increase in the external quantum efficiency of photoelectric conversion of SCs in the near UV range is observed for monolayer films of the 50Al2O3 – 50CuI composition, heat-treated at 280 °C for 30 min, which corresponds to a relative increase in the photocurrent upon exposure to radiation of spectral composition AM1.5 (1000 W/m2 ) by more than 35 %. This confirms the efficiency of using re-emitting Al2O3 – CuI films to increase the efficiency of silicon SCs.

Author Biographies

Gvidona P. Shevchenko, Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus

PhD (chemistry), docent; leading researcher at the laboratory of nanochemistry

Yuliya V. Bokshyts, Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus

PhD (chemistry); researcher at the laboratory of nanochemistry

Catherine A. Kovel, Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus

junior researcher at the laboratory of nanochemistry

Nadzeya V. Shynkevich, Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus

engineer at the department of energy physics, faculty of physics

Alexander V. Mazanik, Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus

PhD (physics and mathematics), docent; head of the department of energy physics, faculty of physics

Dormidont A. Serban, Institute of Applied Physics, 5 Academiei Street, Chisinau, MD-2028, Moldova

PhD (physics and mathematics), full professor; chief researcher

Nicolai N. Curmei, Institute of Applied Physics, 5 Academiei Street, Chisinau, MD-2028, Moldova

PhD (physics and mathematics); senior researcher

Leonid I. Bruk, Institute of Applied Physics, 5 Academiei Street, Chisinau, MD-2028, Moldova

PhD (physics and mathematics), docent; leading researcher

Piotr P. Pershukevich, B. I. Stepanov Institute of Physics, National Academy of Sciences of Belarus, 68-2 Niezaliežnasci Avenue, Minsk 220072, Belarus

PhD (physics and mathematics); senior researcher

References

  1. Sen Z. Solar energy in progress and future research trends. Progress in Energy and Combustion Science. 2004;30(4):367–416. DOI: 10.1016/j.pecs.2004.02.004.
  2. Gremenok VF, Tivanov MS, Zalesskii VB. Solnechnye elementy na osnove poluprovodnikovykh materialov [Solar cells based on semiconductor materials]. Minsk: Izdatel’skii tsentr BGU; 2007. 222 p. Russian.
  3. Malashkevich GE, Shevchenko GP, Bokshyts YuV, Frolova EV, inventors; Stepanov Institute of Physics, National Academy of Sciences of Belarus, assignee. Luminescent film. Belarusian patent 10742. 2008 June 30. Russian.
  4. Shevchenko GP, Piskunovich IYu, Stupak AP, Semkova GI. Oxide – CuI luminescent films. Vestnik BGU. Seriya 2. Khimiya. Biologiya. Geografiya. 2012;1:15–18. Russian.
  5. Malashkevich GE, Shevchenko GP, Vashchenko SV, Denisenko GA, Pershukevich PP. Effect of doping with gold of GeO2 – Eu2O3 – Ag film on their spectral luminescent properties. Izvestiya RAN. Seriya fizicheskaya. 2006;70(11):1662–1667. Russian.
  6. Malashkevich GE, Shevchenko GP, Serezhkina SV, Pershukevich PP, Semkova GI, Glushonok GK. [Influence of the chemical state of silver on the luminescent properties of films of the GeO2 – Eu2O3 – Ag system]. Fizika tverdogo tela. 2007;49(10):1804–1814. Russian.
  7. Malashkevich GE, Chukova OV, Nedilko SG, Shevchenko GP, Bokshits YuV, Kouhar VV. Influence of gold nanoparticles on luminescence of Eu3+ ions sensitized by structural defects in germanate films. Journal of Physical Chemistry C. 2016;120(28): 15369–15377. DOI: 10.1021/acs.jpcc.6b02324.
  8. Shevchenko GP, Bokshits YV, Piskunovitch IY, Zhuravkov VA, Malashkevich GE. Synthesis and spectral-luminescent properties of CuI nano- and microcrystals. In: Borisenko Victor E, Gaponenko SV, Gurin VS, Kam CH, editors. Physics, Chemistry and Application of Nanostructures. Proceedings of International Conference Nanomeeting – 2011; 2011 May 24–27; Minsk, Belarus. Singapore: World Scientific Publishing Company; 2011. p. 385–388. DOI: 10.1142/9789814343909_0092.
  9. Sirimanne PM, Soga Т, Jimbo Т. Identification of various luminescence centers in cui films by cathodoluminescence technique. Journal of Luminescence. 2003;105(2–4):105–109. DOI: 10.1016/S0022-2313(03)00114-5.
  10. Yanyan Xu, Dairong Chen, Xiuling Jiao, Long Ba. PEG-assisted fabrication of single-crystalline CuI nanosheets: a general route to two-dimensional nanostructured materials. Journal of Physical Chemistry C. 2007;111(1):6–9. DOI: 10.1021/jp066649t.
  11. Gogolin O, Mshvelidze G, Tsitsishvili E, Schmidt M, Hepting A, Klingshirn C, et al. Properties of CuI nanocrystallites embedded in a glass matrix: from quantum confinement to bulk-band parameters. Physical Review B. 2000;62(19):13053–13056. DOI: 10.1103/PhysRevB.62.13053.
  12. Xia Ming, Gu Mu, Liu Xiaolin, Liu Bo, Huang Shiming, Ni Chen. Electrical and luminescence properties of Zn2+ doped CuI thin films. Journal of Materials Science: Materials in Electronics. 2015;26:2629–2638. DOI: 10.1007/s10854-015-2735-7.
  13. Nikitenko VA, Stojuhin SG, Kokin SM. Red-orange luminescence of undoped copper iodide crystals in the range of temperature 80–300 K. Zhurnal prikladnoii spektroskopii. 2019;86(5):739–745. Russian.
Published
2021-04-12
Keywords: solar cell, transmission spectra, spectral and luminescent properties, photovoltaic parameters
Supporting Agencies The work was supported by Belarusian Republican Foundation for Fundamental Research (grant No. X19MLDG-002).
How to Cite
Shevchenko, G. P., Bokshyts, Y. V., Kovel, C. A., Shynkevich, N. V., Mazanik, A. V., Serban, D. A., Curmei, N. N., Bruk, L. I., & Pershukevich, P. P. (2021). Re-emitting oxide – copper iodide(I) films for silicone solar cells. Journal of the Belarusian State University. Chemistry, 1, 50-57. https://doi.org/10.33581/2520-257X-2021-1-50-57