Synthesis and structure of novel tripodal ligands based on tetrazol-5-thioles

  • Sergei V. Voitekhovich Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus https://orcid.org/0000-0002-7015-5062
  • Mikhail M. Degtyarik Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus
  • Alexander S. Lyakhov Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus
  • Ludmila S. Ivashkevich Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus
  • Yuri V. Grigoriev Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus
  • Oleg A. Ivashkevich Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus
DOI: https://doi.org/10.33581/2520-257X-2022-2-10-18

Abstract

Novel tripodal ligands (R1N4CS)3CH, where R1 = Me, Ph, were synthesised by alkylation of 1-R-tetrazol-5-thioles with iodoform in alkaline media. These ligands were identified based on data of elemental analysis, nuclear magnetic resonance spectroscopy, thermal analysis, and X-ray diffraction analysis of single crystals.

Author Biographies

Sergei V. Voitekhovich, Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus

PhD (chemistry); leading researcher at the laboratory for chemistry of condensed systems

Mikhail M. Degtyarik, Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus

PhD (chemistry); leading researcher at the laboratory for chemistry of condensed systems

Alexander S. Lyakhov, Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus

PhD (chemistry), docent; leading researcher at the laboratory for chemistry of condensed systems

Ludmila S. Ivashkevich, Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus

PhD (chemistry), docent; head of the laboratory of physico-chemical investigations

Yuri V. Grigoriev, Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus

PhD (chemistry), docent; head of the laboratory for chemistry of condensed systems

Oleg A. Ivashkevich, Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, Belarus

academician of the National Academy of Sciences of Belarus, doctor of science (chemistry), full professor; chief researcher at the laboratory for chemistry of condensed systems

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Published
2022-08-24
Keywords: multipodal ligands, tetrazol-5-thioles, alkylation, X-ray diffraction analysis
Supporting Agencies The research was supported by the Ministry of Education of the Republic of Belarus (assignment 2.1.01.01 of the state program of scientific research «Chemical processes, reagents and technologies, bioregulators and bioorgchemistry»).
How to Cite
Voitekhovich, S. V., Degtyarik, M. M., Lyakhov, A. S., Ivashkevich, L. S., Grigoriev, Y. V., & Ivashkevich, O. A. (2022). Synthesis and structure of novel tripodal ligands based on tetrazol-5-thioles. Journal of the Belarusian State University. Chemistry, 2, 10-18. https://doi.org/10.33581/2520-257X-2022-2-10-18
Issue
No 2 (2022): Journal of the Belarusian State University. Chemistry
Section
Original Articles

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