Magnetic nanoparticles for components of MRI diagnostics and electronic devices

  • Alina S. Korsakova Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieningradskaja Street, Minsk 220006, Belarus https://orcid.org/0000-0001-8898-4726
  • Dzmitry A. Kotsikau Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus
  • Kanstantsin S. Livanovich Institute of Chemistry of New Materials, National Academy of Sciences of Belarus, 36 F. Skaryny Street, Minsk 220141, Belarus https://orcid.org/0000-0003-3083-3962
  • Tatsiana G. Shutava Institute of Chemistry of New Materials, National Academy of Sciences of Belarus, 36 F. Skaryny Street, Minsk 220141, Belarus
  • Yulyan S. Haiduk Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus
  • Vladimir V. Pankov Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus https://orcid.org/0000-0001-5478-0194
DOI: https://doi.org/10.33581/2520-2243-2021-1-12-19

Abstract

The formation of single-phase solid solutions of iron oxide and manganese oxide with a spinel structure in MnxFe3 – xO4 system (x = 0; 0.3; 0.6; 0.8; 1.0; 1.2; 1.4; 1.8) has been established by methods of X-ray phase analysis and infrared spectroscopy. The maximum saturation magnetization was found for the composition Mn0.3 Fe2.7O4 (Ms = 68 A ⋅ m2 ⋅ kg−1 at 300 K and Ms = 85 A ⋅ m2 ⋅ kg−1 at 5 K), which is associated with a change in the cationic distribution over tetrahedral and octahedral voids. The materials obtained were stabilized in the form of colloidal solutions using a number of polyelectrolytes. It was found that poly(diallyldimethylammonium chloride) (PDDA) had the best stabilizing effect due to its structural features. A method for controlling the magnetic properties of magnetite by partial replacement of iron ions in the magnetite structure with manganese is proposed. Changing the magnitude of the magnetization and coercive force is possible by changing the degree of substitution. Relatively high values of specific magnetization, as well as uniformity of magnetic particles in size, can be of practical interest, for the manufacture of contrast agents in MRI diagnostics.

Author Biographies

Alina S. Korsakova, Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieningradskaja Street, Minsk 220006, Belarus

probationer of junior researcher at the laboratory of fuels, vegetable oils and feeds

Dzmitry A. Kotsikau, Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus

docent; associate professor at the department of physical chemistry, faculty of chemistry

Kanstantsin S. Livanovich, Institute of Chemistry of New Materials, National Academy of Sciences of Belarus, 36 F. Skaryny Street, Minsk 220141, Belarus

junior researcher at the laboratory of organic composite materials

Tatsiana G. Shutava, Institute of Chemistry of New Materials, National Academy of Sciences of Belarus, 36 F. Skaryny Street, Minsk 220141, Belarus

PhD (chemistry); leading researcher at the laboratory of organic composite materials

Yulyan S. Haiduk, Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus

researcher at the laboratory of physical chemistry of condensed matter, faculty of chemistry

Vladimir V. Pankov, Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus

doctor of science (chemistry), full professor; professor at the department of physical chemistry, faculty of chemistry

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Published
2021-02-09
Keywords: nanoparticles, saturation magnetization, contrast agents, MRI diagnostics
How to Cite
Korsakova, A. S., Kotsikau, D. A., Livanovich, K. S., Shutava, T. G., Haiduk, Y. S., & Pankov, V. V. (2021). Magnetic nanoparticles for components of MRI diagnostics and electronic devices. Journal of the Belarusian State University. Physics, 1, 12-19. https://doi.org/10.33581/2520-2243-2021-1-12-19
Issue
No 1 (2021): Journal of the Belarusian State University. Physics
Section
Nanomaterials and Nanotechnologies

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