Formation of holographic diffraction gratings in thin films of chalcogenide glassy semiconductors
Abstract
The paper presents a study of the formation of holographic diffraction gratings in thin films of chalcogenide glassy semiconductors. The recording process of holographic gratings at the argon-laser radiation wave length 488 nm and the process of chemical etching that enables the formation of а relief holographic grating are analysed. The optimum conditions for the formation of diffraction gratings in films of arsenic sulfide As2S3 are defined. It is shown that at the 488 nm wave length of an argon laser the optimum exposure comes to ∼5–8 J/cm2. At the recording stage a quasi-phase (relief-phase) grating is formed, with the diffraction efficiency on the order of a few per cent. Etching of the exposed sample with a solution of NaOH alkali in deionised water and isopropanol makes it possible to increase considerably the relief depth and to improve the diffraction efficiency of a thin diffraction grating approximately up to 20 % for the red spectral region, and to approach the maximal value ∼34 % for the near infra-red region. The results of the study considered look promising for the creation of relief holographic gratings which are essential in present-day optical instrument building (production of spectral devices, holographic sights, and the like).
References
- Wenger EF, Melnichuk AV, Stransky AV. Fotostimulirovannye protsessy v khal’kogenidnykh stekloobraznykh poluprovodnikakh i ikh prakticheskoe primenenie [Photostimulated processes in chalcogenide glassy semiconductors and their practical application]. Kyiv: Akademperiodika; 2007. 285 p. Russian.
- Nastas AM, Iovu MS, Tolstik AL. Effect of corona discharge on the optical properties of thin-film Cu – As2Se3 structures. Optics and Spectroscopy. 2020;128(2):231–235. DOI: 10.1134/S0030400X20020174.
- Nastas AM, Iovu MS, Tolstik AL, Stashkevich IV. Corona discharge influence on the formation of holographic gratings in structures of metal – chalcogenide glassy semiconductor. In: Rodin VG, editor. 9th International conference photonics and information optics; 2020 January 29–31; Moscow, Russia. Moscow: National Research Nuclear University MEPHI; 2020. p. 643–644. Russian.
- Collier RJ, Burckhard CB, Lin LH. Optical holography. New York: Academic Press; 1971. 604 p.
- Love JC, Paul KE, Whitesides GM. Fabrication of nanometer-scale features by controlled isotropic wet chemical etching. Advanced Materials. 2001;13(8):604–607.
Copyright (c) 2021 Journal of the Belarusian State University. Physics

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
The authors who are published in this journal agree to the following:
- The authors retain copyright on the work and provide the journal with the right of first publication of the work on condition of license Creative Commons Attribution-NonCommercial. 4.0 International (CC BY-NC 4.0).
- The authors retain the right to enter into certain contractual agreements relating to the non-exclusive distribution of the published version of the work (e.g. post it on the institutional repository, publication in the book), with the reference to its original publication in this journal.
- The authors have the right to post their work on the Internet (e.g. on the institutional store or personal website) prior to and during the review process, conducted by the journal, as this may lead to a productive discussion and a large number of references to this work. (See The Effect of Open Access.)