Optical chemical sensors based on complex compounds

  • Evgeniya Yu. Shachneva Independent researcher, Astrakhan, Russia

Abstract

The material describing various types of optical chemical sensors (detectors, analysers) based on complex compounds is systematised. The characteristics of chemical sensors are given. The classification is presented, the basic principles of operation of the sensors in question and their applications are described. Examples of complex compounds used as thermosensitive pigments produced in different countries with indication of the temperature of colour change are considered. The structures of effective radiating complexes of lanthanides with organic ligands working as emitters are given. The possibilities of using analysers in various industries are emphasised.

Author Biography

Evgeniya Yu. Shachneva, Independent researcher, Astrakhan, Russia

PhD (chemistry), professor of the Russian Academy of Natural History; independent researcher

References

  1. Alov NV, Barbalat YuA, Garmash AV, Dorokhova EN, Dolmanova IF, Zolotov YuA, et al. Osnovy analiticheskoi khimii. Kniga 2, Metody khimicheskogo analiza [Fundamentals of analytical chemistry. Book 2, Methods of chemical analysis]. 2nd edition. Zolotov YuA, editor. Moscow: Vysshaya shkola; 1999. 494 p. Russian.
  2. Yur’eva AV. Fiziko-khimicheskie metody analiza [Physico-chemical methods of analysis]. Omsk: Omsk State Technical University; 2005. 44 p. Russian.
  3. Serov AV, Timchenko VP, Aref’eva LP, Yasnaya MA. Khimicheskie sensory [Chemical sensors]. Stavropol: North-Caucasus Federal University; 2017. 17 p. Russian.
  4. Egorov AA, Egorov MA, Tsareva YuI. Chemical sensors: classification, principles of work, area of application. Physical-chemical Kinetics in Gas Dynamics [Internet]. 2008 [cited 2023 March 21];6. Available from: http://www.chemphys.edu.ru/pdf/2008-01-14-001.pdf. Russian.
  5. Cattrall RW. Chemical sensors. Oxford: Oxford University Press; 1997. 74 p. Russian edition: Cattrall RW. Khimicheskie sensory. Maksimenko OO, translator; Petrukhina OM, editor. Moscow: Nauchnyi mir; 2000. 144 p.
  6. Janata J. Centennial retrospective on chemical sensors. Analytical Chemistry. 2001;73(5):151А–153А. DOI: 10.1021/ac012402a.
  7. Schmidt D, Schwarz W. Optoelektronische Sensorsysteme. Berlin: Verlag Technik; 1988. 80 S. (Reihe Automatisierungstechnik; Band 231). Russian edition: Schmidt D, Schwarz W. Optoelektronnye sensornye sistemy. Gel’man MM, translator. Moscow: Mir; 1991. 95 p.
  8. Eggins BR. Chemical sensors and biosensors. Chichester: John Wiley & Sons; 2002. 300 p. (Analytical techniques in the sciences). Russian edition: Eggins B. Khimicheskie i biologicheskie sensory. Slinkin MA, Zimina TM, Luchinin VV, translators. Moscow: Tekhnosfera; 2005. 336 p. (Mir elektroniki).
  9. Seeboth A, Lӧtzsch D, editors. Thermochromic and thermotropic materials. [S. l.]: Pan Stanford Publishing; 2013. 228 p.
  10. Fernandes LC, Correia DM, García-Astrain C, Pereira N, Tariq M, Esperança JMSS, et al. Ionic-liquid-based printable materials for thermochromic and thermoresistive applications. ACS Applied Materials & Interfaces. 2019;11(22):20316–20324. DOI: 10.1021/acsami.9b00645.
  11. Zhu Dandan, Wang Hongyu. Hexafluorophosphate intercalation into graphite electrode from propylene carbonate/methyl acetate solutions. Electrochimica Acta. 2021;379:138108. DOI: 10.1016/j.electacta.2021.138108.
  12. Yu Hongtao, Li Yunchao, Li Xiaohong, Fan Louzhen, Yang Shihe. Electrochemical preparation of N-doped cobalt oxide nanoparticles with high electrocatalytic activity for the oxygen-reduction reaction. Chemistry – A European Journal. 2014;20(12):3457–3462. DOI: 10.1002/chem.201303814.
  13. Larin VI, Samoilov YA, Shapovalov SA. Investigation of energetics of redox particles processes in electrochemical systems. Kharkov University Bulletin. Chemical Series. 2010;19:101–111. Russian.
  14. Abramovich BG. [Thermal indicators and their application]. Khimiya i khimiki [Internet]. 2008 [cited 2023 March 21];5:19–64. Available from: http://chemistry-chemists.com/N5/19-64.pdf. Russian.
  15. Katkova MA, Vitukhnovsky AG, Bochkarev MN. Coordination compounds of rare-earth metals with organic ligands for electroluminescent diodes. Uspekhi khimii. 2005;74(12):1193–1215. Russian.
  16. Kolechko DV. Sintez i fiziko-khimicheskie svoistva kompleksnykh soedinenii lantanoidov s proizvodnymi ariloksiuksusnoi kisloty [Synthesis and physico-chemical properties of complex compounds of lanthanides with derivatives of aryloxyacetic acid] [dissertation]. Krasnodar: [s. n.]; 2008. 129 p. Russian.
  17. Il’ichev VA. Kompleksy redkozemel’nykh metallov s geterotsiklicheskimi ligandami dlya organicheskikh svetoizluchayushchikh diodov [Complexes of rare-earth metals with heterocyclic ligands for organic light-emitting diodes] [dissertation]. Nizhny Novgorod: [s. n.]; 2011. 118 p. Russian.
  18. Lepikh Ya, Smyntyna VA. [Functional materials based on complex compounds of germanium]. Pis’ma v ZhTF. 2000;26(4):72–76. Russian.
  19. Maslov LP, Rumyantseva VD, Mironov AF, inventors; Lomonosov Moscow State Academy of Fine Chemical Technology, assignee. Datchik gazoobraznogo ammiaka i sposob ego izgotovleniya s ispol’zovaniem metallokompleksov porfirinov [The sensor of gaseous ammonia and the method of its manufacture using porphyrin metal complexes]. Russian Federation patent RU 2172486C2. 2001 August 20. Russian.
  20. Grebnev VV, Mal’chikov GD, Golubev ON, Fesik EV, inventors; Grebnev VV, Mal’chikov GD, assignee. Sposob izgotovleniya rutenievykh elektrodov elektrokhimicheskogo datchika s tverdym elektrolitom [Method of manufacturing ruthenium electrodes of an electrochemical sensor with a solid electrolyte]. Russian Federation patent RU 2342652C2. 2008 December 27. Russian.
  21. Skopenko VV, Tsivadze AYu, Savranskii LI, Garnovskii AD. Koordinatsionnaya khimiya [Coordination chemistry]. Moscow: Akademkniga; 2007. 487 p. Russian.
  22. Khentov VYa, Semchenko VV, Shachneva EYu. Protsessy kompleksoobrazovaniya prirodnogo i tekhnogennogo proiskhozhdeniya [Processes of complex formation of natural and technogenic origin]. Moscow: Rusains; 2017. 266 p. Russian.
Published
2023-10-27
Keywords: sensors, optical chemical sensors, complex compounds, thermosensitive pigments
How to Cite
Shachneva, E. Y. (2023). Optical chemical sensors based on complex compounds. Journal of the Belarusian State University. Physics, 3, 10-21. Retrieved from https://journals.bsu.by/index.php/physics/article/view/5560
Issue
No 3 (2023): Journal of the Belarusian State University. Physics
Section
Optics and Spectroscopy

Copyright (c) 2023 Journal of the Belarusian State University. Physics

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

The authors who are published in this journal agree to the following:

  1. The authors retain copyright on the work and provide the journal with the right of first publication of the work on condition of license Creative Commons Attribution-NonCommercial. 4.0 International (CC BY-NC 4.0).
  2. The authors retain the right to enter into certain contractual agreements relating to the non-exclusive distribution of the published version of the work (e.g. post it on the institutional repository, publication in the book), with the reference to its original publication in this journal.
  3. The authors have the right to post their work on the Internet (e.g. on the institutional store or personal website) prior to and during the review process, conducted by the journal, as this may lead to a productive discussion and a large number of references to this work. (See The Effect of Open Access.)