Controlling H*- and J-aggregation of an indotricarbocyanine dye in aqueous solutions of inorganic salts

  • Nikita V. Belko Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus
  • Michael P. Samtsov A. N. Sevchenko Institute of Applied Physical Problems, Belarusian State University, 7 Kurčatava Street, Minsk 220045, Belarus https://orcid.org/0000-0002-8392-7463
  • Anatoly P. Lugovski A.N. Sevchenko Institute of Applied Physical Problems of the Belaruain State University

Abstract

Aggregation process of a symmetrical cationic indotricarbocyanine dye in aqueous medium was studied. It was shown that self-assembled H*-aggregates with an absorption peak at 514 nm as well as J-aggregates with an absorption peak at 777 nm can be obtained. Both of the aggregate types are non-fluorescent. High concentration of a desired aggregate type can be obtained and stabilized by changing ionic strength and pH of the solution. At ionic strength of 170 mmol/L and pH 7.4 J-aggregates are stable. Decreasing pH as well as ionic strength leads to demise of J-aggregates and concomitant formation of H*-aggregates. Increasing temperature leads to a faster H*-aggregate formation. The type of aggregates can be changed by heating and subsequent cooling of the solution. An organic compound forming both H*- and J-aggregates has never been observed before. The fact that the H*- and J-bands are narrow, the shift between them is significant, the J-band is located in the far-red spectral region, and the type of aggregates can be controlled makes these objects promising for future applications.

Author Biographies

Nikita V. Belko, Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus

postgraduate student at the department of laser physics and spectroscopy, faculty of physics

Michael P. Samtsov, A. N. Sevchenko Institute of Applied Physical Problems, Belarusian State University, 7 Kurčatava Street, Minsk 220045, Belarus

doctor of science (physics and mathematics), docent; head of the laboratory of spectroscopy

Anatoly P. Lugovski, A.N. Sevchenko Institute of Applied Physical Problems of the Belaruain State University

PhD (chemistry); leading researcher at the laboratory of spectroscopy

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Published
2020-06-02
Keywords: cyanine dyes, H*-aggregates, J-aggregates, absorption spectroscopy, self-assembly
Supporting Agencies This research has been financially supported by the State Program of Scientific Research of the Republic of Belarus «Chemical technologies and materials» (assignment 5.23), State Program of Scientific Research of the Republic of Belarus «Photonics, opto- and microelectronics» (assignment 1.2.10).
How to Cite
Belko, N. V., Samtsov, M. P., & Lugovski, A. P. (2020). Controlling H*- and J-aggregation of an indotricarbocyanine dye in aqueous solutions of inorganic salts. Journal of the Belarusian State University. Physics, 2, 19-27. https://doi.org/10.33581/2520-2243-2020-2-19-27